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The role of organometallic copper (III) complexes in homogeneous catalysis

Organometallic CuIII species have been invoked in many copper-catalyzed reactions, but until recently, experimental evidences were lacking. The advent of new spectroscopic techniques and the characterization of simple and stable catalyst models have been key to gain clear mechanistic insights into these important reactions. In this perspective, we will discuss these discoveries and the corresponding mechanistic proposals that derive from important reactions such as nucleophilic organocuprate chemistry for C-C bond formation, C-heteroatom cross-coupling reactions (Ullmann condensation reactions and halide-exchange processes) and direct C-H bond functionalizations catalyzed by copper

We acknowledge financial support from European Research Council for Starting Grant Project ERC-2011-StG-277801 to X. R., MICINN of Spain (INNPLANTA project INP-2011-0059-PCT-420000-ACT1 to X. R., CTQ2009-08464/BQU to Dr M. Costas and PhD FPU grant to A. C.), Consolider-Ingenio CSD2010-00065, and the Catalan DIUE of the Generalitat de Catalunya (2009SGR637). X. R. thanks ANC for guiding us to freedom and also thanks an ICREA-Academia award

© Chemical Science, 2013, vol. 4, p. 2301-2318

Royal Society of Chemistry (RSC)

Author: Casitas Montero, Alícia
Ribas Salamaña, Xavi
Date: 2013
Abstract: Organometallic CuIII species have been invoked in many copper-catalyzed reactions, but until recently, experimental evidences were lacking. The advent of new spectroscopic techniques and the characterization of simple and stable catalyst models have been key to gain clear mechanistic insights into these important reactions. In this perspective, we will discuss these discoveries and the corresponding mechanistic proposals that derive from important reactions such as nucleophilic organocuprate chemistry for C-C bond formation, C-heteroatom cross-coupling reactions (Ullmann condensation reactions and halide-exchange processes) and direct C-H bond functionalizations catalyzed by copper
We acknowledge financial support from European Research Council for Starting Grant Project ERC-2011-StG-277801 to X. R., MICINN of Spain (INNPLANTA project INP-2011-0059-PCT-420000-ACT1 to X. R., CTQ2009-08464/BQU to Dr M. Costas and PhD FPU grant to A. C.), Consolider-Ingenio CSD2010-00065, and the Catalan DIUE of the Generalitat de Catalunya (2009SGR637). X. R. thanks ANC for guiding us to freedom and also thanks an ICREA-Academia award
Format: application/pdf
ISSN: 2041-6520 (versió paper)
2041-6539 (versió electrònica)
Document access: http://hdl.handle.net/10256/10203
Language: eng
Publisher: Royal Society of Chemistry (RSC)
Collection: MICINN/PN 2010-2012/CTQ2009-08464
MICINN/PN 2010-2016/CSD2010-00065
AGAUR/2009-2014/2009 SGR-637
MICINN/PN 2011/INP-2011-0059-PCT-420000
Reproducció digital del document publicat a: http://dx.doi.org/10.1039/c3sc21818j
Articles publicats (D-Q)
info:eu-repo/grantAgreement/EC/FP7/277801
Is part of: © Chemical Science, 2013, vol. 4, p. 2301-2318
Rights: Tots els drets reservats
Subject: Compostos organometàl·lics
Organometallic compounds
Catàlisi homogènia
Homogeneous catalysis
Title: The role of organometallic copper (III) complexes in homogeneous catalysis
Type: info:eu-repo/semantics/article
Repository: DUGiDocs

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