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Garcia Borrà s, Marc
Osuna Oliveras, SÃlvia Swart, Marcel Luis Luis, Josep Maria Solà i Puig, Miquel |
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2013 | |
In this work we show that the regioselectivity of the Diels-Alder, 1,3-dipolar, and carbene cycloadditions to C60 changes from the usual [6,6] addition in neutral species to the [5,6] attack when the number of electrons added to the fullerenic cage increases. Changes in the aromaticity of the five- and six-membered rings of C60 during the reduction process provide a rationale to understand this regioselectivity change | |
application/pdf | |
1359-7345 (versió paper) 1364-548X (versió electrònica) |
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http://hdl.handle.net/10256/10206 | |
eng | |
Royal Society of Chemistry (RSC) | |
MICINN/PN 2012-2014/CTQ2011-23156 MICINN/PN 2012-2014/CTQ2011-25086 AGAUR/2009-2014/2009 SGR-637 AGAUR/2009-2014/2009 SGR-528 Reproducció digital del document publicat a: http://dx.doi.org/10.1039/c2cc38390j Articles publicats (D-Q) info:eu-repo/grantAgreement/EC/FP7/252856 |
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© Chemical Communications, 2013, vol. 49, p. 1220-1222 | |
Tots els drets reservats | |
Diels-Alder, Reacció de
Diels-Alder reaction Reaccions quÃmiques regioselectives Regioselectivity Chemical reactions Fullerenes Ful·lerens Aromaticitat (QuÃmica) Aromaticity (Chemistry) |
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Electrochemical control of the regioselectivity in the exohedral functionalization of C60: The role of aromaticity | |
info:eu-repo/semantics/article | |
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