Ítem
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Ministerio de Ciencia e Innovación (Espanya)
Generalitat de Catalunya. Agència de Gestió d’Ajuts Universitaris i de Recerca |
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Garcia Borràs, Marc
Osuna Oliveras, Sílvia Swart, Marcel Luis Luis, Josep Maria Solà i Puig, Miquel |
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| 2013 | |
| In this work we show that the regioselectivity of the Diels-Alder, 1,3-dipolar, and carbene cycloadditions to C60 changes from the usual [6,6] addition in neutral species to the [5,6] attack when the number of electrons added to the fullerenic cage increases. Changes in the aromaticity of the five- and six-membered rings of C60 during the reduction process provide a rationale to understand this regioselectivity change | |
| application/pdf | |
| http://hdl.handle.net/10256/10206 | |
| eng | |
| Royal Society of Chemistry (RSC) | |
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info:eu-repo/semantics/altIdentifier/doi/10.1039/c2cc38390j info:eu-repo/semantics/altIdentifier/issn/1359-7345 info:eu-repo/semantics/altIdentifier/eissn/1364-548X info:eu-repo/grantAgreement/MICINN//CTQ2011-23156/ES/AVANCES EN CATALISIS Y AROMATICIDAD/ info:eu-repo/grantAgreement/MICINN//CTQ2011-25086/ES/MODELIZACION MULTIESCALAR EN (BIO)QUIMICA/ AGAUR/2009-2014/2009 SGR-637 AGAUR/2009-2014/2009 SGR-528 info:eu-repo/grantAgreement/EC/FP7/252856/EU/Enzyme Design of Medical Interest/MEDENZYMEDESIGN |
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| Tots els drets reservats | |
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Diels-Alder, Reacció de
Diels-Alder reaction Reaccions químiques regioselectives Regioselectivity Chemical reactions Fullerenes Ful·lerens Aromaticitat (Química) Aromaticity (Chemistry) |
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| Electrochemical control of the regioselectivity in the exohedral functionalization of C60: The role of aromaticity | |
| info:eu-repo/semantics/article | |
| DUGiDocs |
