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Electronic effects on single-site iron catalysts for water oxidation

Getting in tune: Systematic tuning of the electronic properties of modular non-heme iron coordination complexes can be used to extract important information on the reaction mechanism and intermediates, which, in turn, help to explain the activity of these systems as water oxidation catalysts

We would like to thank Prof. J. Mayer, Dr. L. Que, Jr., Dr. W. R. Browne and Dr. X. Ribas for their comments, the European Research Council for FP7-PEOPLE-2010-ERG-268445 and ERC-2009-StG-239910, MICINN for CTQ2012-37420-C02-01 (M. C.), and CTQ2011-23156/BQU (J. M. L.) for the Ramon y Cajal contract (J. Ll.-F) and for PhD grants (I. G.-B. and I. P.), Generalitat de Catalunya for an ICREA Academia Award and Catexel for their generous gift of tritosylTACN

© Chemistry - A European Journal, 2013, vol. 19, núm. 25, p. 8042-8047

Wiley-VCH Verlag

Author: Codolà Duch, Zoel
Garcia Bosch, Isaac
Acuña-Parés, Ferran
Prat Casellas, Irene
Luis Luis, Josep Maria
Costas Salgueiro, Miquel
Lloret Fillol, Julio
Date: 2013 June
Abstract: Getting in tune: Systematic tuning of the electronic properties of modular non-heme iron coordination complexes can be used to extract important information on the reaction mechanism and intermediates, which, in turn, help to explain the activity of these systems as water oxidation catalysts
We would like to thank Prof. J. Mayer, Dr. L. Que, Jr., Dr. W. R. Browne and Dr. X. Ribas for their comments, the European Research Council for FP7-PEOPLE-2010-ERG-268445 and ERC-2009-StG-239910, MICINN for CTQ2012-37420-C02-01 (M. C.), and CTQ2011-23156/BQU (J. M. L.) for the Ramon y Cajal contract (J. Ll.-F) and for PhD grants (I. G.-B. and I. P.), Generalitat de Catalunya for an ICREA Academia Award and Catexel for their generous gift of tritosylTACN
Format: application/pdf
ISSN: 0947-6539 (versió paper)
1521-3765 (versió electrònica)
Document access: http://hdl.handle.net/10256/10915
Language: eng
Publisher: Wiley-VCH Verlag
Collection: MINECO/PN 2013-2015/CTQ2012-37420-C02-01
MICINN/PN 2012-2014/CTQ2011-23156
Reproducció digital del document publicat a: http://dx.doi.org/10.1002/chem.201301112
Articles publicats (D-Q)
Is part of: © Chemistry - A European Journal, 2013, vol. 19, núm. 25, p. 8042-8047
Rights: Tots els drets reservats
Subject: Catalitzadors de ferro
Iron catalysts
Catàlisi homogènia
Homogeneous catalysis
Aigua -- Oxidació
Water -- Oxidation
Title: Electronic effects on single-site iron catalysts for water oxidation
Type: info:eu-repo/semantics/article
Repository: DUGiDocs

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