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Assessment of the effect of UV and chlorination in the transformation of fragrances in aqueous samples

The removal and transformation of 15 common fragrance allergens and two polycyclic musks in water samples were studied using UV irradiation and chlorination treatments. The monitoring of the reaction was carried out by a HS-SPME method coupled to GC-MS analysis. Different behaviours were observed depending on the compound and the treatment applied. Elimination experiments showed that all target compounds were affected by at least one of the two treatments. A total of 15 UV transformation products were detected and chemical structures were proposed for five of them. In the chlorination experiments, only galaxolide and benzyl cinnamate transformation products were observed

A. Godayol gratefully acknowledges a grant from the Generalitat de Catalunya (2013FI_B2 00126). R. Gonzalez-Olmos thanks MICINN for the Juan de la Cierva fellowship (JCI-2010-07104). This work was funded by the Ministerio de Innovacion y Ciencia (MICINN) (CTQ2011-24114). The authors are grateful to A. Roglans and A. Pla for their help with the investigation of the reaction pathways

© Chemosphere, 2015, vol. 125, p. 25-32

Elsevier

Author: Godayol Boix, Anna
González Olmos, Rafael
Sánchez Navarro, Juan Manuel
Anticó i Daró, Ma. Enriqueta
Date: 2015 January 1
Abstract: The removal and transformation of 15 common fragrance allergens and two polycyclic musks in water samples were studied using UV irradiation and chlorination treatments. The monitoring of the reaction was carried out by a HS-SPME method coupled to GC-MS analysis. Different behaviours were observed depending on the compound and the treatment applied. Elimination experiments showed that all target compounds were affected by at least one of the two treatments. A total of 15 UV transformation products were detected and chemical structures were proposed for five of them. In the chlorination experiments, only galaxolide and benzyl cinnamate transformation products were observed
A. Godayol gratefully acknowledges a grant from the Generalitat de Catalunya (2013FI_B2 00126). R. Gonzalez-Olmos thanks MICINN for the Juan de la Cierva fellowship (JCI-2010-07104). This work was funded by the Ministerio de Innovacion y Ciencia (MICINN) (CTQ2011-24114). The authors are grateful to A. Roglans and A. Pla for their help with the investigation of the reaction pathways
Format: application/pdf
ISSN: 0045-6535
Document access: http://hdl.handle.net/10256/11268
Language: eng
Publisher: Elsevier
Collection: MICINN/PN 2012-2015/CTQ2011-24114
AGAUR/2013FI-B2 00126
Reproducció digital del document publicat a: http://dx.doi.org/10.1016/j.chemosphere.2015.01.009
Articles publicats (D-Q)
Is part of: © Chemosphere, 2015, vol. 125, p. 25-32
Rights: Tots els drets reservats
Subject: Radiació ultraviolada
Ultraviolet radiation
Aigua -- Depuració -- Cloració
Water -- Purification -- Chlorination
Title: Assessment of the effect of UV and chlorination in the transformation of fragrances in aqueous samples
Type: info:eu-repo/semantics/article
Repository: DUGiDocs

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