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A simple catalytic system based on PdCl2 (CH3CN) 2 in water for cross-coupling reactions using diazonium salts

Aryl-heteroaryl and heteroaryl-heteroaryl compounds are obtained through the Suzuki-Miyaura cross-coupling reactions between diazonium salts and potassium trifluoroborates using PdCl2(CH3CN)2 as the catalyst in water and in the absence of any additive, ligand or base. In addition, the same mild catalytic system is effective for the Matsuda-Heck reaction between several monoolefins with aryldiazonium salts

Financial support from MICINN (CTQ2011-23121) of Spain and ’Generalitat de Catalunya’ (2009SGR637) is acknowledged

info:eu-repo/grantAgreement/MICINN//CTQ2011-23121/ES/APLICACIONES CATALITICAS DE COMPUESTOS DE RODIO, PALADIO Y NIQUEL EN SINTESIS ORGANICA. METODOLOGIA Y ESTUDIOS MECANISTICOS./

Elsevier

Manager: Ministerio de Ciencia e Innovación (Espanya)
Generalitat de Catalunya. Agència de Gestió d’Ajuts Universitaris i de Recerca
Author: El Bakouri, Ouissam
Fernández Wang, Martí
Brun Massó, Sandra
Pla i Quintana, Anna
Roglans i Ribas, Anna
Abstract: Aryl-heteroaryl and heteroaryl-heteroaryl compounds are obtained through the Suzuki-Miyaura cross-coupling reactions between diazonium salts and potassium trifluoroborates using PdCl2(CH3CN)2 as the catalyst in water and in the absence of any additive, ligand or base. In addition, the same mild catalytic system is effective for the Matsuda-Heck reaction between several monoolefins with aryldiazonium salts
Financial support from MICINN (CTQ2011-23121) of Spain and ’Generalitat de Catalunya’ (2009SGR637) is acknowledged
Format: application/pdf
Document access: http://hdl.handle.net/10256/11338
Language: eng
Publisher: Elsevier
Collection: info:eu-repo/semantics/altIdentifier/doi/10.1016/j.tet.2013.09.010
info:eu-repo/semantics/altIdentifier/issn/0040-4020
AGAUR/2009-2014/2009 SGR-637
Is part of: info:eu-repo/grantAgreement/MICINN//CTQ2011-23121/ES/APLICACIONES CATALITICAS DE COMPUESTOS DE RODIO, PALADIO Y NIQUEL EN SINTESIS ORGANICA. METODOLOGIA Y ESTUDIOS MECANISTICOS./
Rights: Tots els drets reservats
Subject: Reaccions químiques
Chemical reactions
Compost de diazoni
Diazonium compounds
Title: A simple catalytic system based on PdCl2 (CH3CN) 2 in water for cross-coupling reactions using diazonium salts
Type: info:eu-repo/semantics/article
Repository: DUGiDocs

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