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A simple catalytic system based on PdCl2 (CH3CN) 2 in water for cross-coupling reactions using diazonium salts

Aryl-heteroaryl and heteroaryl-heteroaryl compounds are obtained through the Suzuki-Miyaura cross-coupling reactions between diazonium salts and potassium trifluoroborates using PdCl2(CH3CN)2 as the catalyst in water and in the absence of any additive, ligand or base. In addition, the same mild catalytic system is effective for the Matsuda-Heck reaction between several monoolefins with aryldiazonium salts

Financial support from MICINN (CTQ2011-23121) of Spain and ’Generalitat de Catalunya’ (2009SGR637) is acknowledged

© Tetrahedron, 2013, vol. 69, núm. 46, p. 9761-9765

Elsevier

Manager: Ministerio de Ciencia e Innovación (Espanya)
Generalitat de Catalunya. Agència de Gestió d’Ajuts Universitaris i de Recerca
Author: El Bakouri, Ouissam
Fernández Wang, Martí
Brun Massó, Sandra
Pla i Quintana, Anna
Roglans i Ribas, Anna
Abstract: Aryl-heteroaryl and heteroaryl-heteroaryl compounds are obtained through the Suzuki-Miyaura cross-coupling reactions between diazonium salts and potassium trifluoroborates using PdCl2(CH3CN)2 as the catalyst in water and in the absence of any additive, ligand or base. In addition, the same mild catalytic system is effective for the Matsuda-Heck reaction between several monoolefins with aryldiazonium salts
Financial support from MICINN (CTQ2011-23121) of Spain and ’Generalitat de Catalunya’ (2009SGR637) is acknowledged
Format: application/pdf
Citation: 019226
ISSN: 0040-4020
Document access: http://hdl.handle.net/10256/11338
Language: eng
Publisher: Elsevier
Collection: MICINN/PN 2012-2014/CTQ2011-23121
AGAUR/2009-2014/2009 SGR-637
Reproducció digital del document publicat a: http://dx.doi.org/10.1016/j.tet.2013.09.010
Articles publicats (D-Q)
Is part of: © Tetrahedron, 2013, vol. 69, núm. 46, p. 9761-9765
Rights: Tots els drets reservats
Subject: Reaccions químiques
Chemical reactions
Compost de diazoni
Diazonium compounds
Title: A simple catalytic system based on PdCl2 (CH3CN) 2 in water for cross-coupling reactions using diazonium salts
Type: info:eu-repo/semantics/article
Repository: DUGiDocs

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