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Nickel (0) complexes of polyunsaturated azamacrocyclic ligands

A series of nickel(0) complexes, 3, 4, and 5, containing unsaturated 15-membered azamacrocyclic ligands have been synthesized. Structural characterization of the complexes is based on NMR spectroscopy, X-ray diffraction analysis, and differential scanning calorimetry. In addition, the catalytic activity of the complexes in the Suzuki-Miyaura cross-coupling of arylboronic acids and aryl halides has been tested

The project was funded by the program Acciones Integradas Hispano-Alemanas between Germany (DAAD, BMBF) and Spain (MICINN, Spanish Ministry of Science and Innovation, Project AIB2010DE-00262). Financial support from the MICINN (Projects CTQ2008-05409, CTQ2011-23121) and the Generalitat de Catalunya (Project 2009SGR637) is also gratefully acknowledged. S.B. thanks the University of Girona for a predoctoral grant

info:eu-repo/grantAgreement/MICINN//CTQ2011-23121/ES/APLICACIONES CATALITICAS DE COMPUESTOS DE RODIO, PALADIO Y NIQUEL EN SINTESIS ORGANICA. METODOLOGIA Y ESTUDIOS MECANISTICOS./

info:eu-repo/grantAgreement/MICINN//CTQ2008-05409-C02-02/ES/SINTESIS, REACTIVIDAD Y APLICACIONES DE MACROCICLOS POLIINSATURADOS Y SUS PRECURSORES. ESTUDIOS MECANISTICOS MEDIANTE ESI-MS./

American Chemical Society (ACS)

Manager: Ministerio de Ciencia e Innovaci贸n (Espanya)
Ministerio de Educaci贸n y Ciencia (Espanya)
Generalitat de Catalunya. Ag猫ncia de Gesti贸 d鈥橝juts Universitaris i de Recerca
Author: Brun Mass贸, Sandra
Pla i Quintana, Anna
Roglans i Ribas, Anna
P枚rschke, Klaus Richard
Goddard, Richard
Abstract: A series of nickel(0) complexes, 3, 4, and 5, containing unsaturated 15-membered azamacrocyclic ligands have been synthesized. Structural characterization of the complexes is based on NMR spectroscopy, X-ray diffraction analysis, and differential scanning calorimetry. In addition, the catalytic activity of the complexes in the Suzuki-Miyaura cross-coupling of arylboronic acids and aryl halides has been tested
The project was funded by the program Acciones Integradas Hispano-Alemanas between Germany (DAAD, BMBF) and Spain (MICINN, Spanish Ministry of Science and Innovation, Project AIB2010DE-00262). Financial support from the MICINN (Projects CTQ2008-05409, CTQ2011-23121) and the Generalitat de Catalunya (Project 2009SGR637) is also gratefully acknowledged. S.B. thanks the University of Girona for a predoctoral grant
Format: application/pdf
Document access: http://hdl.handle.net/10256/11343
Language: eng
Publisher: American Chemical Society (ACS)
Collection: info:eu-repo/semantics/altIdentifier/doi/10.1021/om201271y
info:eu-repo/semantics/altIdentifier/issn/0276-7333
info:eu-repo/semantics/altIdentifier/eissn/1520-6041
AGAUR/2009-2014/2009 SGR-637
Is part of: info:eu-repo/grantAgreement/MICINN//CTQ2011-23121/ES/APLICACIONES CATALITICAS DE COMPUESTOS DE RODIO, PALADIO Y NIQUEL EN SINTESIS ORGANICA. METODOLOGIA Y ESTUDIOS MECANISTICOS./
info:eu-repo/grantAgreement/MICINN//CTQ2008-05409-C02-02/ES/SINTESIS, REACTIVIDAD Y APLICACIONES DE MACROCICLOS POLIINSATURADOS Y SUS PRECURSORES. ESTUDIOS MECANISTICOS MEDIANTE ESI-MS./
Rights: Tots els drets reservats
Subject: N铆quel -- Compostos
Nickel compounds
Metalls de transici贸 -- Compostos
Transition metal compounds
Title: Nickel (0) complexes of polyunsaturated azamacrocyclic ligands
Type: info:eu-repo/semantics/article
Repository: DUGiDocs

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