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Nickel (0) complexes of polyunsaturated azamacrocyclic ligands

A series of nickel(0) complexes, 3, 4, and 5, containing unsaturated 15-membered azamacrocyclic ligands have been synthesized. Structural characterization of the complexes is based on NMR spectroscopy, X-ray diffraction analysis, and differential scanning calorimetry. In addition, the catalytic activity of the complexes in the Suzuki-Miyaura cross-coupling of arylboronic acids and aryl halides has been tested

The project was funded by the program Acciones Integradas Hispano-Alemanas between Germany (DAAD, BMBF) and Spain (MICINN, Spanish Ministry of Science and Innovation, Project AIB2010DE-00262). Financial support from the MICINN (Projects CTQ2008-05409, CTQ2011-23121) and the Generalitat de Catalunya (Project 2009SGR637) is also gratefully acknowledged. S.B. thanks the University of Girona for a predoctoral grant

© Organometallics, 2012, vol. 31, núm. 5, p. 1983-1990

American Chemical Society (ACS)

Author: Brun Massó, Sandra
Pla i Quintana, Anna
Roglans i Ribas, Anna
Pörschke, Klaus Richard
Goddard, Richard
Date: 2012 March 12
Abstract: A series of nickel(0) complexes, 3, 4, and 5, containing unsaturated 15-membered azamacrocyclic ligands have been synthesized. Structural characterization of the complexes is based on NMR spectroscopy, X-ray diffraction analysis, and differential scanning calorimetry. In addition, the catalytic activity of the complexes in the Suzuki-Miyaura cross-coupling of arylboronic acids and aryl halides has been tested
The project was funded by the program Acciones Integradas Hispano-Alemanas between Germany (DAAD, BMBF) and Spain (MICINN, Spanish Ministry of Science and Innovation, Project AIB2010DE-00262). Financial support from the MICINN (Projects CTQ2008-05409, CTQ2011-23121) and the Generalitat de Catalunya (Project 2009SGR637) is also gratefully acknowledged. S.B. thanks the University of Girona for a predoctoral grant
Format: application/pdf
ISSN: 0276-7333 (versió paper)
1520-6041 (versió electrònica)
Document access: http://hdl.handle.net/10256/11343
Language: eng
Publisher: American Chemical Society (ACS)
Collection: MICINN/PN 2012-2014/CTQ2011-23121
MEC/PN 2009-2011/CTQ2008-05409-C02-02
AGAUR/2009-2014/2009 SGR-637
Reproducció digital del document publicat a: http://dx.doi.org/10.1021/om201271y
Articles publicats (D-Q)
Is part of: © Organometallics, 2012, vol. 31, núm. 5, p. 1983-1990
Rights: Tots els drets reservats
Subject: Níquel -- Compostos
Nickel compounds
Metalls de transició -- Compostos
Transition metal compounds
Title: Nickel (0) complexes of polyunsaturated azamacrocyclic ligands
Type: info:eu-repo/semantics/article
Repository: DUGiDocs

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