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π [pi] Aromaticity and Three-Dimensional Aromaticity: Two sides of the Same Coin?

A bridge between classical organic polycyclic aromatic hydrocarbons (PAH) and closo borohydride clusters is established by showing that they share a common origin regulated by the number of valence electrons in an electronic confined space. Application of the proposed electronic confined space analogy (ECSA) method to archetypal PAHs leads to the conclusion that the 4n+2 Wade-Mingos rule for three-dimensional closo boranes is equivalent to the (4n+2) pi Huckel rule for two-dimensional PAHs. More importantly, use of ECSA allows design of new interesting fused closo boranes which can be a source of inspiration for synthetic chemists

This work was supported by the Ministerio de Ciencia e Innovacion (projects CTQ2011-23156/BQU, CTQ2011-25086/BQU, CTQ2010-16237, and CTQ2013-44670-R), the Generalitat de Catalunya (projects 2009SGR279, 2009SGR637, 2009SGR528, 2014SGR931, XRQTC, ICREA Academia 2009 for MS), the FEDER fund, and the Centre de Serveis Cientifics i Academics de Catalunya

© Angewandte Chemie International Edition, 2014, vol. 53, p.12191-12195

Wiley-VCH Verlag

Manager: Ministerio de Ciencia e Innovación (Espanya)
Generalitat de Catalunya. Agència de Gestió d’Ajuts Universitaris i de Recerca
Author: Poater i Teixidor, Jordi
Solà i Puig, Miquel
Viñas, Clara
Teixidor Bombardó, Francesc
Date: 2014
Abstract: A bridge between classical organic polycyclic aromatic hydrocarbons (PAH) and closo borohydride clusters is established by showing that they share a common origin regulated by the number of valence electrons in an electronic confined space. Application of the proposed electronic confined space analogy (ECSA) method to archetypal PAHs leads to the conclusion that the 4n+2 Wade-Mingos rule for three-dimensional closo boranes is equivalent to the (4n+2) pi Huckel rule for two-dimensional PAHs. More importantly, use of ECSA allows design of new interesting fused closo boranes which can be a source of inspiration for synthetic chemists
This work was supported by the Ministerio de Ciencia e Innovacion (projects CTQ2011-23156/BQU, CTQ2011-25086/BQU, CTQ2010-16237, and CTQ2013-44670-R), the Generalitat de Catalunya (projects 2009SGR279, 2009SGR637, 2009SGR528, 2014SGR931, XRQTC, ICREA Academia 2009 for MS), the FEDER fund, and the Centre de Serveis Cientifics i Academics de Catalunya
Format: application/pdf
ISSN: 1433-7851
1521-3773
Document access: http://hdl.handle.net/10256/11358
Language: eng
Publisher: Wiley-VCH Verlag
Collection: MICINN/PN 2012-2014/CTQ2011-23156
MICINN/PN 2012-2014/CTQ2011-25086
AGAUR/2009-2014/2009 SGR-637
AGAUR/2009-2014/2009 SGR-528
AGAUR/2014-2016/2014 SGR-931
Reproducció digital del document publicat a: http://dx.doi.org/10.1002/anie.201407359
Articles publicats (D-Q)
Is part of: © Angewandte Chemie International Edition, 2014, vol. 53, p.12191-12195
Rights: Tots els drets reservats
Subject: Aromaticitat (Química)
Aromaticity (Chemistry)
Hidrocarburs
Hydrocarbons
Title: π [pi] Aromaticity and Three-Dimensional Aromaticity: Two sides of the Same Coin?
Type: info:eu-repo/semantics/article
Repository: DUGiDocs

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