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| Ministerio de Ciencia e Innovación (Espanya) | |
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Dakkach, Mohamed
Fontrodona, Xavier Parella Coll, Teodor Atlamsani, Ahmed Romero GarcÃa, Isabel RodrÃguez Pizarro, Montserrat |
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| 2011 February 11 | |
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A new ruthenium aquo catalyst with the formula trans-[Ru(II)(CN-Me)(trpy) OH2](PF6)2 [where trpy=2,2a:6′,2″- terpyridine and CN-Me=3-methyl-1-(pyridin-2-yl)-imidazolylidene] has been prepared and thoroughly characterized by spectroscopic and electrochemical techniques. The complex has been tested in epoxidation catalysis both in dichloromethane and dichloromethane:ionic liquid media, displaying excellent performances and selectivities. Reuse of the catalyst in ionic liquid:solvent media has been explored for the first time in ruthenium-mediated epoxidation catalysis and its performance is fully maintained for up to ten runs This project has been financed by MICINN of Spain through projects CTQ2007-60476/PPQ, CTQ2010-21532-C02-01 and CTQ2009-08328 |
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| application/pdf | |
| http://hdl.handle.net/10256/11725 | |
| eng | |
| Wiley-VCH Verlag | |
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info:eu-repo/semantics/altIdentifier/doi/10.1002/adsc.201000686 info:eu-repo/semantics/altIdentifier/issn/1615-4150 info:eu-repo/semantics/altIdentifier/eissn/1615-4169 info:eu-repo/grantAgreement/MICINN//CTQ2010-21532-C02-01/ES/MIMETIZACION DE PROCESOS BIOINORGANICOS Y APLICACIONES CATALITICAS CON COMPUESTOS DE METALES DE TRANSICION./ |
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| Tots els drets reservats | |
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Ruteni -- Compostos
Ruthenium compounds Epòxids Epoxy compounds Catà lisi Catalysis Oxidació Oxidation |
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| A novel carbene ruthenium complex as reusable and selective two-electron catalyst for alkene epoxidation | |
| info:eu-repo/semantics/article | |
| DUGiDocs |
