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A water soluble Mn (II) polymer with aqua metal bridges

The first water soluble and crystallographically determined polynuclear Mn(ii) complex, with water molecules bridging every two Mn centers, is reported. This is an unusual feature in 1D oligomer Mn(ii) compounds with a nuclearity higher than 2. The polymer structure is largely preserved in water

We thank the Spanish MINECO (CTQ2010-21532-C02-01, CTQ2010-16237, CTQ2009-06959), Generalitat de Catalunya (2009/SGR/00279) and Ministry of Education and Academy of Sciences of the Czech Republic (MSM0021620857, IAAX00320901) for financial support, and Alexander Jigounov for SAXS/WAXS measurements

Royal Society of Chemistry (RSC)

Manager: Ministerio de Ciencia e Innovación (Espanya)
Author: Fontanet Cepeda, Mònica
Rodríguez Pizarro, Montserrat
Romero García, Isabel
Fontrodona, Xavier
Teixidor Bombardó, Francesc
Viñas, Clara
Aliaga Alcalde, Núria
Matějíček, Pavel
Abstract: The first water soluble and crystallographically determined polynuclear Mn(ii) complex, with water molecules bridging every two Mn centers, is reported. This is an unusual feature in 1D oligomer Mn(ii) compounds with a nuclearity higher than 2. The polymer structure is largely preserved in water
We thank the Spanish MINECO (CTQ2010-21532-C02-01, CTQ2010-16237, CTQ2009-06959), Generalitat de Catalunya (2009/SGR/00279) and Ministry of Education and Academy of Sciences of the Czech Republic (MSM0021620857, IAAX00320901) for financial support, and Alexander Jigounov for SAXS/WAXS measurements
Format: application/pdf
Document access: http://hdl.handle.net/10256/11727
Language: eng
Publisher: Royal Society of Chemistry (RSC)
Collection: info:eu-repo/semantics/altIdentifier/doi/10.1039/C3DT00097D
info:eu-repo/semantics/altIdentifier/issn/1477-9226
info:eu-repo/semantics/altIdentifier/eissn/1477-9234
info:eu-repo/grantAgreement/MICINN//CTQ2010-21532-C02-01/ES/MIMETIZACION DE PROCESOS BIOINORGANICOS Y APLICACIONES CATALITICAS CON COMPUESTOS DE METALES DE TRANSICION./
Rights: Tots els drets reservats
Subject: Compostos polimèrics
Polymeric composites
Reaccions químiques
Chemical reactions
Manganès -- Compostos
Manganese compounds
Title: A water soluble Mn (II) polymer with aqua metal bridges
Type: info:eu-repo/semantics/article
Repository: DUGiDocs

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