Ítem
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Ministerio de Economía y Competitividad (Espanya)
Generalitat de Catalunya. Agència de Gestió d’Ajuts Universitaris i de Recerca |
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Hassanpour, Azin
Acuña-Parés, Ferran Luis Luis, Josep Maria Cussó Forest, Olaf Morales de la Rosa, Silvia Campos Martín, José Miguel Fierro, Jose L.G. Costas Salgueiro, Miquel Lloret Fillol, Julio Mas-Ballesté, Rubén |
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| 2015 | |
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Herein we show that species generated upon reaction of α-[Fe(CF3SO3)2(BPMCN)] (BPMCN = N,N′-bis(2-pyridylmethyl)-trans-1,2-diaminocyclohexane) with H2O2 (putatively [FeV(O)(OH)(BPMCN)]) is able to efficiently oxidize H2 to H2O even in the presence of organic substrates, while species formed in the presence of acetic acid (putatively [FeV(O)(OAc)(BPMCN)]) prefer organic substrate oxidation over H2 activation. Mechanistic implications have been analysed with the aid of computational methods This work was supported by Spanish Ministerio de Economia y Competitividad (CTQ2012-37420-C02-02 and 01) European Research Council (StG 239910), and Generalitat de Catalunya (2014 SGR 862 and ICREA Academia award to MC). J.Ll.-F. thanks the CELLEX foundation for the starting career program for financial support |
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| application/pdf | |
| http://hdl.handle.net/10256/12250 | |
| eng | |
| Royal Society of Chemistry (RSC) | |
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info:eu-repo/semantics/altIdentifier/doi/10.1039/c5cc06402c info:eu-repo/semantics/altIdentifier/issn/1359-7345 info:eu-repo/semantics/altIdentifier/eissn/1364-548X AGAUR/2014-2016/2014 SGR-862 info:eu-repo/grantAgreement/EC/FP7/239910/EU/Bio-inspired Design of Catalysts for Selective Oxidations of C-H and C=C Bonds/BIDECASEOX |
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| info:eu-repo/grantAgreement/MINECO//CTQ2012-37420-C02-01/ES/DISEÑO BIOINSPIRADO DE CATALIZADORES PARA LA OXIDACION DE ENLACES C-H, C=C Y AGUA/ | |
| Tots els drets reservats | |
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Oxidació
Oxidation |
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| H2 oxidation versus organic substrate oxidation in non-heme iron mediated reactions with H2O2 | |
| info:eu-repo/semantics/article | |
| DUGiDocs |
