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Simple and Sustainable Copper-O 2 Chemistry towards High-Value Products

Oxygen meets its end, or does it? Straightforward Cu-catalyzed preparation of α-ketoamides has been recently achieved through oxidative coupling of aryl acetaldehydes and arylamines by using O2 as the terminal oxidant. The work represents a remarkable example of a simple and sustainable transformation to yield elaborate and more complex biologically relevant oxidized products from readily available reagents under mild conditions

Anna Company and Xavi Ribas are acknowledged for a critical reading of this manuscript and valuable opinions. Financial support by ICREA-Academia Awards, Catalan SGR 2009-SGR637, MICINN-Spain (CTQ2009-08464/BQU), the European Research Foundation for the Project ERC-2009-StG-239910 and Consolider Ingenio/CSD2010-00065

Wiley-VCH Verlag

Manager: Ministerio de Ciencia e Innovación (Espanya)
Generalitat de Catalunya. Agència de Gestió d’Ajuts Universitaris i de Recerca
Author: Costas Salgueiro, Miquel
Date: 2012
Abstract: Oxygen meets its end, or does it? Straightforward Cu-catalyzed preparation of α-ketoamides has been recently achieved through oxidative coupling of aryl acetaldehydes and arylamines by using O2 as the terminal oxidant. The work represents a remarkable example of a simple and sustainable transformation to yield elaborate and more complex biologically relevant oxidized products from readily available reagents under mild conditions
Anna Company and Xavi Ribas are acknowledged for a critical reading of this manuscript and valuable opinions. Financial support by ICREA-Academia Awards, Catalan SGR 2009-SGR637, MICINN-Spain (CTQ2009-08464/BQU), the European Research Foundation for the Project ERC-2009-StG-239910 and Consolider Ingenio/CSD2010-00065
Format: application/pdf
Document access: http://hdl.handle.net/10256/12252
Language: eng
Publisher: Wiley-VCH Verlag
Collection: info:eu-repo/semantics/altIdentifier/doi/10.1002/cctc.201100350
info:eu-repo/semantics/altIdentifier/issn/1867-3880
info:eu-repo/semantics/altIdentifier/eissn/1867-3899
MICINN/PN 2010-2012/ CTQ2009-08464
MICINN/PN 2010-2016/CSD2010-00065
AGAUR/2009-2014/2009 SGR-637
info:eu-repo/grantAgreement/EC/FP7/239910/EU/Bio-inspired Design of Catalysts for Selective Oxidations of C-H and C=C Bonds/BIDECASEOX
Rights: Tots els drets reservats
Subject: Synthetic methods
Activació (Química)
Activation (Chemistry)
Coure
Copper
Catàlisi
Catalysis
Title: Simple and Sustainable Copper-O 2 Chemistry towards High-Value Products
Type: info:eu-repo/semantics/article
Repository: DUGiDocs

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