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Simple and Sustainable Copper-O 2 Chemistry towards High-Value Products

Oxygen meets its end, or does it? Straightforward Cu-catalyzed preparation of α-ketoamides has been recently achieved through oxidative coupling of aryl acetaldehydes and arylamines by using O2 as the terminal oxidant. The work represents a remarkable example of a simple and sustainable transformation to yield elaborate and more complex biologically relevant oxidized products from readily available reagents under mild conditions

Anna Company and Xavi Ribas are acknowledged for a critical reading of this manuscript and valuable opinions. Financial support by ICREA-Academia Awards, Catalan SGR 2009-SGR637, MICINN-Spain (CTQ2009-08464/BQU), the European Research Foundation for the Project ERC-2009-StG-239910 and Consolider Ingenio/CSD2010-00065

© ChemCatChem, 2012, vol. 4, núm. 2, p. 175-176

Wiley-VCH Verlag

Author: Costas Salgueiro, Miquel
Date: 2012
Abstract: Oxygen meets its end, or does it? Straightforward Cu-catalyzed preparation of α-ketoamides has been recently achieved through oxidative coupling of aryl acetaldehydes and arylamines by using O2 as the terminal oxidant. The work represents a remarkable example of a simple and sustainable transformation to yield elaborate and more complex biologically relevant oxidized products from readily available reagents under mild conditions
Anna Company and Xavi Ribas are acknowledged for a critical reading of this manuscript and valuable opinions. Financial support by ICREA-Academia Awards, Catalan SGR 2009-SGR637, MICINN-Spain (CTQ2009-08464/BQU), the European Research Foundation for the Project ERC-2009-StG-239910 and Consolider Ingenio/CSD2010-00065
Format: application/pdf
ISSN: 1867-3880 (versió paper)
1867-3899 (versió electrònica)
Document access: http://hdl.handle.net/10256/12252
Language: eng
Publisher: Wiley-VCH Verlag
Collection: MICINN/PN 2010-2012/ CTQ2009-08464
MICINN/PN 2010-2016/CSD2010-00065
AGAUR/2009-2014/2009 SGR-637
Reproducció digital del document publicat a: http://dx.doi.org/10.1002/cctc.201100350
Articles publicats (D-Q)
info:eu-repo/grantAgreement/EC/FP7/239910
Is part of: © ChemCatChem, 2012, vol. 4, núm. 2, p. 175-176
Rights: Tots els drets reservats
Subject: Synthetic methods
Activació (Química)
Activation (Chemistry)
Coure
Copper
Catàlisi
Catalysis
Title: Simple and Sustainable Copper-O 2 Chemistry towards High-Value Products
Type: info:eu-repo/semantics/article
Repository: DUGiDocs

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