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Ministerio de Ciencia e Innovación (Espanya)
Ministerio de EconomÃa y Competitividad (Espanya) Generalitat de Catalunya. Agència de Gestió d’Ajuts Universitaris i de Recerca |
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GarcÃa Simón, Cristina
Garcia Borrà s, Marc Gómez MartÃn, Laura Parella Coll, Teodor Osuna Oliveras, SÃlvia Juanhuix, Jordi Imaz, Inhar Maspoch, Daniel Costas Salgueiro, Miquel Ribas Salamaña, Xavi |
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2014 | |
Since fullerenes are available in macroscopic quantities from fullerene soot, large efforts have been geared toward designing efficient strategies to obtain highly pure fullerenes, which can be subsequently applied in multiple research fields. Here we present a supramolecular nanocage synthesized by metal-directed self-assembly, which encapsulates fullerenes of different sizes. Direct experimental evidence is provided for the 1:1 encapsulation of ​C60, ​C70, C76, C78 and C84, and solid state structures for the host–guest adducts with ​C60 and ​C70 have been obtained using X-ray synchrotron radiation. Furthermore, we design a washing-based strategy to exclusively extract pure ​C60 from a solid sample of cage charged with a mixture of fullerenes. These results showcase an attractive methodology to selectively extract ​C60 from fullerene mixtures, providing a platform to design tuned cages for selective extraction of higher fullerenes. The solid-phase fullerene encapsulation and liberation represent a twist in host–guest chemistry for molecular nanocage structures This work was supported by grants from the European Research Council (Starting Grant Projects ERC-2011-StG-277801 and ERC-2009-StG-239910), the Spanish MICINN (CTQ2012-37420-C02-01/BQU, CTQ2012-32436, CTQ2011-23156/BQU, CTQ2011-25086/BQU, Consolider-Ingenio CSD2010-00065, INNPLANTA project INP-2011-0059-PCT-420000-ACT1, MAT2012-30994, a RyC contract to I.I., a JdC contract JCI-2012-14438 and CIG (FP7-PEOPLE-2013-CIG-630978) to S.O. and a PhD grant AP2010-2517 to M.G.B.) and the Generalitat de Catalunya (2009SGR637 and a PhD grant to C.G.S.) |
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application/pdf | |
http://hdl.handle.net/10256/12257 | |
eng | |
Macmillan | |
info:eu-repo/semantics/altIdentifier/doi/10.1038/ncomms6557 info:eu-repo/semantics/altIdentifier/issn/2041-1723 MICINN/PN 2011/INP-2011-0059-PCT-420000 info:eu-repo/grantAgreement/MICINN//CTQ2011-23156/ES/AVANCES EN CATALISIS Y AROMATICIDAD/ info:eu-repo/grantAgreement/MICINN//CTQ2011-25086/ES/MODELIZACION MULTIESCALAR EN (BIO)QUIMICA/ MICINN/PN 2010-2016/CSD2010-00065 AGAUR/2009-2014/2009 SGR-637 info:eu-repo/grantAgreement/EC/FP7/239910/EU/Bio-inspired Design of Catalysts for Selective Oxidations of C-H and C=C Bonds/BIDECASEOX info:eu-repo/grantAgreement/EC/FP7/277801/EU/Sustainable C-X and C-H Functionalization Catalyzed by Copper(III) Species/SUSCATCU3 info:eu-repo/grantAgreement/EC/FP7/630978/EU/Computational Exploration of Directed Evolution rules for tuning enzymatic activities/DIREVENZYME |
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info:eu-repo/grantAgreement/MINECO//CTQ2012-37420-C02-01/ES/DISEÑO BIOINSPIRADO DE CATALIZADORES PARA LA OXIDACION DE ENLACES C-H, C=C Y AGUA/ | |
Tots els drets reservats | |
Ful·lerens
Fullerenes Nanotecnologia Nanotechnology |
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Sponge-like molecular cage for purification of fullerenes | |
info:eu-repo/semantics/article | |
DUGiDocs |