Ítem
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Ministerio de Ciencia e Innovación (Espanya)
Generalitat de Catalunya. Agència de Gestió d’Ajuts Universitaris i de Recerca |
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Prat Casellas, Irene
Gómez Martín, Laura Canta i Roldós, Mercè Ribas Salamaña, Xavi Costas Salgueiro, Miquel |
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| 2013 | |
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Many are called but few are chosen: A nonheme iron complex catalyzes the oxidation of alkyl C[BOND]H bonds by using H2O2 as the oxidant, showing an enhanced selectivity for secondary over tertiary C[BOND]H bonds (see scheme) Financial support by the European Research Council for project ERC-29910, the MCYT of Spain through project CTQ200908464/BQU to M.C., and Consolider Ingenio/CSD2010-00065. I.P. and M.C thank the MICINN and Generalitat de Catalunya, respectively, for Ph.D. grants. M.C. and X.R. thank the Generalitat de Catalunya for 2009SGR637 and ICREA Acad mia Awards. Catexcel is acknowledged for a generous gift of tritosyltriazacyclononane |
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| application/pdf | |
| http://hdl.handle.net/10256/12260 | |
| eng | |
| Wiley-VCH Verlag | |
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info:eu-repo/semantics/altIdentifier/doi/10.1002/chem.201203281 info:eu-repo/semantics/altIdentifier/issn/0947-6539 info:eu-repo/semantics/altIdentifier/eissn/1521-3765 MICINN/PN 2010-2016/CSD2010-00065 MICINN/PN 2010-2012/ CTQ2009-08464 AGAUR/2009-2014/2009 SGR-637 info:eu-repo/grantAgreement/EC/FP7/239910/EU/Bio-inspired Design of Catalysts for Selective Oxidations of C-H and C=C Bonds/BIDECASEOX |
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| Tots els drets reservats | |
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Catàlisi
Catalysis Catàlisi homogènia Homogeneous catalysis Aigua oxigenada Hydrogen peroxide Ferro Iron Catalitzadors de ferro Iron catalysts |
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| An iron catalyst for oxidation of alkyl C-H bonds showing enhanced selectivity for methylenic sites | |
| info:eu-repo/semantics/article | |
| DUGiDocs |
