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An iron catalyst for oxidation of alkyl C-H bonds showing enhanced selectivity for methylenic sites

Many are called but few are chosen: A nonheme iron complex catalyzes the oxidation of alkyl C[BOND]H bonds by using H2O2 as the oxidant, showing an enhanced selectivity for secondary over tertiary C[BOND]H bonds (see scheme)

Financial support by the European Research Council for project ERC-29910, the MCYT of Spain through project CTQ200908464/BQU to M.C., and Consolider Ingenio/CSD2010-00065. I.P. and M.C thank the MICINN and Generalitat de Catalunya, respectively, for Ph.D. grants. M.C. and X.R. thank the Generalitat de Catalunya for 2009SGR637 and ICREA Acad mia Awards. Catexcel is acknowledged for a generous gift of tritosyltriazacyclononane

© Chemistry-A European Journal, 2013, vol. 19, núm. 6, p. 1908-1913

Wiley-VCH Verlag

Author: Prat Casellas, Irene
Gómez Martín, Laura
Canta i Roldós, Mercè
Ribas Salamaña, Xavi
Costas Salgueiro, Miquel
Date: 2013
Abstract: Many are called but few are chosen: A nonheme iron complex catalyzes the oxidation of alkyl C[BOND]H bonds by using H2O2 as the oxidant, showing an enhanced selectivity for secondary over tertiary C[BOND]H bonds (see scheme)
Financial support by the European Research Council for project ERC-29910, the MCYT of Spain through project CTQ200908464/BQU to M.C., and Consolider Ingenio/CSD2010-00065. I.P. and M.C thank the MICINN and Generalitat de Catalunya, respectively, for Ph.D. grants. M.C. and X.R. thank the Generalitat de Catalunya for 2009SGR637 and ICREA Acad mia Awards. Catexcel is acknowledged for a generous gift of tritosyltriazacyclononane
Format: application/pdf
ISSN: 0947-6539 (versió paper)
1521-3765 (versió electrònica)
Document access: http://hdl.handle.net/10256/12260
Language: eng
Publisher: Wiley-VCH Verlag
Collection: MICINN/PN 2010-2016/CSD2010-00065
MICINN/PN 2010-2012/ CTQ2009-08464
AGAUR/2009-2014/2009 SGR-637
Reproducció digital del document publicat a: http://dx.doi.org/10.1002/chem.201203281
Articles publicats (D-Q)
info:eu-repo/grantAgreement/EC/FP7/239910
Is part of: © Chemistry-A European Journal, 2013, vol. 19, núm. 6, p. 1908-1913
Rights: Tots els drets reservats
Subject: Catàlisi
Catalysis
Catàlisi homogènia
Homogeneous catalysis
Aigua oxigenada
Hydrogen peroxide
Ferro
Iron
Catalitzadors de ferro
Iron catalysts
Title: An iron catalyst for oxidation of alkyl C-H bonds showing enhanced selectivity for methylenic sites
Type: info:eu-repo/semantics/article
Repository: DUGiDocs

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