Ítem
| Ministerio de Ciencia e Innovación (Espanya) | |
|
Schröder, Kristin
Join, Benoët Amali, Arlin Jose Junge, Kathrin Ribas Salamaña, Xavi Costas Salgueiro, Miquel Beller, Matthias |
|
| 2011 | |
|
El mateix article està publicat en alemany a l’edició alemanya d’ ’Angewandte Chemie’ (ISSN 0044-8249, EISSN 1521-3757), 2011, vol. 123, núm. 6, p.1461–1465. DOI http://dx.doi.org/10.1002/ange.201004623 It’s no sacrifice: A bio-inspired iron system, in which a β-keto ester serves as a sacrificial cosubstrate, readily epoxidizes olefins under ambient conditions with air. Aromatic olefins are oxidized in high yields with excellent chemoselectivity. Mechanistic investigations point out substantial differences to well-known radical-based autoxidations M.C. thanks MICINN for project CTQ2009-08464/BQU, Generalitat de Catalunya for an ICREA Academia Award, and UdG STR for experimental support |
|
| application/pdf | |
| http://hdl.handle.net/10256/12261 | |
| eng | |
| Wiley-VCH Verlag | |
|
info:eu-repo/semantics/altIdentifier/doi/10.1002/anie.201004623 info:eu-repo/semantics/altIdentifier/issn/1433-7851 info:eu-repo/semantics/altIdentifier/eissn/1521-3773 MICINN/PN 2010-2012/ CTQ2009-08464 |
|
| Tots els drets reservats | |
|
Epòxids
Epoxy compounds Imidazoles Ferro Iron Alquens Alkenes |
|
| A biomimetic iron catalyst for the epoxidation of olefins with molecular oxygen at room temperature | |
| info:eu-repo/semantics/article | |
| DUGiDocs |
