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A biomimetic iron catalyst for the epoxidation of olefins with molecular oxygen at room temperature

El mateix article està publicat en alemany a l’edició alemanya d’ ’Angewandte Chemie’ (ISSN 0044-8249, EISSN 1521-3757), 2011, vol. 123, núm. 6, p.1461–1465. DOI http://dx.doi.org/10.1002/ange.201004623

It’s no sacrifice: A bio-inspired iron system, in which a β-keto ester serves as a sacrificial cosubstrate, readily epoxidizes olefins under ambient conditions with air. Aromatic olefins are oxidized in high yields with excellent chemoselectivity. Mechanistic investigations point out substantial differences to well-known radical-based autoxidations

M.C. thanks MICINN for project CTQ2009-08464/BQU, Generalitat de Catalunya for an ICREA Academia Award, and UdG STR for experimental support

Wiley-VCH Verlag

Manager: Ministerio de Ciencia e Innovación (Espanya)
Author: Schröder, Kristin
Join, Benoët
Amali, Arlin Jose
Junge, Kathrin
Ribas Salamaña, Xavi
Costas Salgueiro, Miquel
Beller, Matthias
Date: 2011
Abstract: El mateix article està publicat en alemany a l’edició alemanya d’ ’Angewandte Chemie’ (ISSN 0044-8249, EISSN 1521-3757), 2011, vol. 123, núm. 6, p.1461–1465. DOI http://dx.doi.org/10.1002/ange.201004623
It’s no sacrifice: A bio-inspired iron system, in which a β-keto ester serves as a sacrificial cosubstrate, readily epoxidizes olefins under ambient conditions with air. Aromatic olefins are oxidized in high yields with excellent chemoselectivity. Mechanistic investigations point out substantial differences to well-known radical-based autoxidations
M.C. thanks MICINN for project CTQ2009-08464/BQU, Generalitat de Catalunya for an ICREA Academia Award, and UdG STR for experimental support
Format: application/pdf
Document access: http://hdl.handle.net/10256/12261
Language: eng
Publisher: Wiley-VCH Verlag
Collection: info:eu-repo/semantics/altIdentifier/doi/10.1002/anie.201004623
info:eu-repo/semantics/altIdentifier/issn/1433-7851
info:eu-repo/semantics/altIdentifier/eissn/1521-3773
MICINN/PN 2010-2012/ CTQ2009-08464
Rights: Tots els drets reservats
Subject: Epòxids
Epoxy compounds
Imidazoles
Ferro
Iron
Alquens
Alkenes
Title: A biomimetic iron catalyst for the epoxidation of olefins with molecular oxygen at room temperature
Type: info:eu-repo/semantics/article
Repository: DUGiDocs

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