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Transformation products of emerging contaminants in the environment and high-resolution mass spectrometry: A new horizon

It is crucial to study the presence of transformation products (TPs) of emerging contaminants that can be potentially found in the environment after biological or chemical degradation. This review focuses on the potential and shortcomings of high-resolution mass spectrometry (HRMS) to identify these TPs, with emphasis on recent developments in mass analyzers, data evaluation, and compound identification workflows and applications. Advances in HRMS technologies, including direct introduction or in-line chromatographic separation modes, ionization techniques, mass analyzers, and detection methods, have led to powerful tools to assess the molecular changes and the opening of new horizons to identify unknown molecules. Advances in HRMS pertaining to the generation of analytical data for the main methods to identify TPs, including nontargeted and targeted approaches as they are applied to elucidate the structure of TPs, are also discussed

This work was supported by the Spanish Ministry of Economy and Competitiveness through the projects BAssessing and Predicting Effects on Water Quantity and Quality in Iberian Rivers Caused by Global Change (SCARCE) (no. CSD2009-00065; http://www.scarceconsolider.es) and BEvaluation of Emerging Contaminants in the Turia River Basins: From Basic Research to the Application of Environmental Forensics (EMERFOR) (GCL2011-29703-C02-02; http://mefturia.es)

Springer-Verlag

Manager: Ministerio de Ciencia e Innovación (Espanya)
Author: Picó, Yolanda
Barceló i Cullerés, Damià
Abstract: It is crucial to study the presence of transformation products (TPs) of emerging contaminants that can be potentially found in the environment after biological or chemical degradation. This review focuses on the potential and shortcomings of high-resolution mass spectrometry (HRMS) to identify these TPs, with emphasis on recent developments in mass analyzers, data evaluation, and compound identification workflows and applications. Advances in HRMS technologies, including direct introduction or in-line chromatographic separation modes, ionization techniques, mass analyzers, and detection methods, have led to powerful tools to assess the molecular changes and the opening of new horizons to identify unknown molecules. Advances in HRMS pertaining to the generation of analytical data for the main methods to identify TPs, including nontargeted and targeted approaches as they are applied to elucidate the structure of TPs, are also discussed
This work was supported by the Spanish Ministry of Economy and Competitiveness through the projects BAssessing and Predicting Effects on Water Quantity and Quality in Iberian Rivers Caused by Global Change (SCARCE) (no. CSD2009-00065; http://www.scarceconsolider.es) and BEvaluation of Emerging Contaminants in the Turia River Basins: From Basic Research to the Application of Environmental Forensics (EMERFOR) (GCL2011-29703-C02-02; http://mefturia.es)
Format: application/pdf
Document access: http://hdl.handle.net/10256/12593
Language: eng
Publisher: Springer-Verlag
Collection: info:eu-repo/semantics/altIdentifier/doi/10.1007/s00216-015-8739-6
info:eu-repo/semantics/altIdentifier/issn/1618-2642
info:eu-repo/semantics/altIdentifier/eissn/1618-2650
info:eu-repo/grantAgreement/MICINN//CSD2009-00065/ES/Evaluación y predicción de los efectos del cambio global en la cantidad y la calidad del agua en ríos ibéricos/
Rights: Tots els drets reservats
Subject: Contaminants emergents en l’aigua
Emerging contaminants in water
Cromatografia de líquids
Liquid chromatography
Espectrometria de masses
Mass spectrometry
Title: Transformation products of emerging contaminants in the environment and high-resolution mass spectrometry: A new horizon
Type: info:eu-repo/semantics/article
Repository: DUGiDocs

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