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Nitrous oxide activation by a cobalt(ii) complex for aldehyde oxidation under mild conditions

Nitrous oxide (N2O) is a waste gas produced in many industrial processes with an important environmental impact. Thus, its application as an oxidant is highly desirable because it produces innocuous N2 as a by-product. In this work we report a new cobalt(ii) complex that reacts with N2O under mild conditions and the catalytic application of this system to carry out the oxidation of aldehydes

Financial support for this work was provided by the European Commission (2011-CIG-303522 to A. C.) and the MINECO of Spain (“Ramón y Cajal” contract and CTQ2013-43012-P to A. C.)

Royal Society of Chemistry (RSC)

Manager: Ministerio de Economía y Competitividad (Espanya)
Author: Corona Prieto, Teresa
Company Casadevall, Anna
Abstract: Nitrous oxide (N2O) is a waste gas produced in many industrial processes with an important environmental impact. Thus, its application as an oxidant is highly desirable because it produces innocuous N2 as a by-product. In this work we report a new cobalt(ii) complex that reacts with N2O under mild conditions and the catalytic application of this system to carry out the oxidation of aldehydes
Financial support for this work was provided by the European Commission (2011-CIG-303522 to A. C.) and the MINECO of Spain (“Ramón y Cajal” contract and CTQ2013-43012-P to A. C.)
Format: application/pdf
Document access: http://hdl.handle.net/10256/13279
Language: eng
Publisher: Royal Society of Chemistry (RSC)
Collection: info:eu-repo/semantics/altIdentifier/doi/10.1039/c6dt01704e
info:eu-repo/semantics/altIdentifier/issn/1477-9226
info:eu-repo/semantics/altIdentifier/eissn/1477-9234
info:eu-repo/grantAgreement/MINECO//CTQ2013-43012-P/ES/INVESTIGACIONES MECANISTICAS PARA SINTESIS ORGANICA SOSTENIBLE VIA ACTIVACION DE PEQUEÑAS MOLECULAS GASEOSAS Y DE ENLACES C-H CON METALES DE LA PRIMERA SERIE DE TRANSICION/
info:eu-repo/grantAgreement/EC/FP7/303522/EU/Key insights into oxidation chemistry through synthetic systems: N2O activation with first-row transition-metals and O2 activation in heterobimetallic Fe-Ni systems/NEWOXMET
Rights: Tots els drets reservats
Subject: Cobalt -- Compostos
Cobalt compounds
Aldehids -- Oxidació
Aldehydes -- Oxidation
Title: Nitrous oxide activation by a cobalt(ii) complex for aldehyde oxidation under mild conditions
Type: info:eu-repo/semantics/article
Repository: DUGiDocs

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