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Evaluation of an olefin metathesis pre-catalyst with a bulky and electron-rich N-heterocyclic carbene

The commercially-available metathesis pre-catalyst M23 has been evaluated alongside new complex [RuCl2((3-phenyl)indenylidene)(PPh3)(SIPrOMe)] (1), which bears a para-methoxy-substituted N-heterocyclic carbene ligand. Several model metathesis reactions could be conducted using only parts-per-million levels of ruthenium catalyst. The effects of the different NHC ligands on reactivity have been explored

SPN thanks the European Research Council (227817) (Advanced Investigator Award ‘FUNCAT’), the EU (CP-FP 211468) (Seventh Framework Programme Project ‘EUMET’), and the Engineering and Physical Sciences Research Council for funding. SPN is a Royal Society Wolfson Merit Award holder. AP thanks the Spanish MINECO for a Ram on y Cajal contract (RYC-2009-05226) and European Commission for a Career Integration Grant (CIG09-GA-2011- 293900)

© Journal of Organometallic Chemistry, 2015, vol. 780, p. 43-48

Elsevier

Author: Manzini, Simone
Cavallo, Luigi
Nolan, Steven P.
Urbina-Blanco, Cesar A.
Nelson, David J.
Poater Teixidor, Albert
Lebl, Tomas
Meiries, Sébastien
Slawin, Alexandra M. Z.
Falivene, Laura
Date: 2015 March 15
Abstract: The commercially-available metathesis pre-catalyst M23 has been evaluated alongside new complex [RuCl2((3-phenyl)indenylidene)(PPh3)(SIPrOMe)] (1), which bears a para-methoxy-substituted N-heterocyclic carbene ligand. Several model metathesis reactions could be conducted using only parts-per-million levels of ruthenium catalyst. The effects of the different NHC ligands on reactivity have been explored
SPN thanks the European Research Council (227817) (Advanced Investigator Award ‘FUNCAT’), the EU (CP-FP 211468) (Seventh Framework Programme Project ‘EUMET’), and the Engineering and Physical Sciences Research Council for funding. SPN is a Royal Society Wolfson Merit Award holder. AP thanks the Spanish MINECO for a Ram on y Cajal contract (RYC-2009-05226) and European Commission for a Career Integration Grant (CIG09-GA-2011- 293900)
Format: application/pdf
Citation: 0022328X
Document access: http://hdl.handle.net/10256/13286
Language: eng
Publisher: Elsevier
Collection: MINECO/PN 2012-2015/RYC-2009-05226
Reproducció digital del document publicat a: http://dx.doi.org/10.1016/j.jorganchem.2014.12.040
Articles publicats (D-Q)
info:eu-repo/grantAgreement/EC/FP7/293900
Is part of: © Journal of Organometallic Chemistry, 2015, vol. 780, p. 43-48
Rights: Tots els drets reservats
Subject: Funcional de densitat, Teoria del
Density functionals
Metàtesi (Química)
Metathesis (Chemistry)
Ruteni
Ruthenium
Alquens
Alkenes
Title: Evaluation of an olefin metathesis pre-catalyst with a bulky and electron-rich N-heterocyclic carbene
Type: info:eu-repo/semantics/article
Repository: DUGiDocs

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