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Highly active phosphine-free bifunctional iron complex for hydrogenation of bicarbonate and reductive amination

Based on a "transition metal frustrated Lewis pair" approach, a cyclopentadienone iron tricarbonyl complex has been designed and applied in the reductive amination and hydrogenation of bicarbonate. This well-defined phosphine-free complex displays the best activities reported to date for an iron complex in the reduction of bicarbonate into formate and in reductive amination

A.P. thanks the Spanish MINECO for a Ramón y Cajal contract (RYC-2009–05226) and the European Commission for a Career Integration Grant (CIG09-GA-2011–293900)

© Chemistry - A European Journal, 2015, vol. 21, núm. 19, p. 7066-7070

Wiley

Manager: Ministerio de Economía y Competitividad (Espanya)
Author: Thai, Trieu Tien
Mérel, Delphine S.
Poater Teixidor, Albert
Gaillard, Sylvain
Renaud, Jean Luc
Abstract: Based on a "transition metal frustrated Lewis pair" approach, a cyclopentadienone iron tricarbonyl complex has been designed and applied in the reductive amination and hydrogenation of bicarbonate. This well-defined phosphine-free complex displays the best activities reported to date for an iron complex in the reduction of bicarbonate into formate and in reductive amination
A.P. thanks the Spanish MINECO for a Ramón y Cajal contract (RYC-2009–05226) and the European Commission for a Career Integration Grant (CIG09-GA-2011–293900)
Format: application/pdf
ISSN: 0947-6539 (versió paper)
1521-3765 (versió electrònica)
Document access: http://hdl.handle.net/10256/13292
Language: eng
Publisher: Wiley
Collection: MINECO/PN 2012-2015/RYC-2009-05226
Reproducció digital del document publicat a: http://dx.doi.org/10.1002/chem.201500720
Articles publicats (D-Q)
info:eu-repo/grantAgreement/EC/FP7/293900
Is part of: © Chemistry - A European Journal, 2015, vol. 21, núm. 19, p. 7066-7070
Rights: Tots els drets reservats
Subject: Catàlisi homogènia
Homogeneous catalysis
Hidrogenació
Hydrogenation
Reducció química
Reduction (Chemistry)
Title: Highly active phosphine-free bifunctional iron complex for hydrogenation of bicarbonate and reductive amination
Type: info:eu-repo/semantics/article
Repository: DUGiDocs

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