Ítem
| Ministerio de Economía y Competitividad (Espanya) | |
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Wappel, Julia
Fischer, Roland C. Cavallo, Luigi Slugovc, Christian Poater Teixidor, Albert |
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| 28 gener 2016 | |
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A straightforward synthesis utilizing the ring-opening metathesis polymerization (ROMP) reaction is described for acid-triggered
N,O-chelating ruthenium-based pre-catalysts bearing one or two 8-quinolinolate ligands. The innovative pre-catalysts were tested
regarding their behavior in ROMP and especially for their use in the synthesis of poly(dicyclopentadiene) (pDCPD). Bearing either
the common phosphine leaving ligand in the first and second Grubbs olefin metathesis catalysts, or the Ru–O bond cleavage for the
next Hoveyda-type catalysts, this work is a step forward towards the control of polymer functionalization and living or switchable
polymerizations A.P. thanks the Spanish MINECO for a project CTQ2014-59832-JIN, and European Commission for a Career Integration Grant (CIG09-GA-2011-293900 |
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| application/pdf | |
| http://hdl.handle.net/10256/13310 | |
| eng | |
| Beilstein-Institut | |
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info:eu-repo/semantics/altIdentifier/doi/10.3762/bjoc.12.17 info:eu-repo/semantics/altIdentifier/eissn/1860-5397 info:eu-repo/grantAgreement/MINECO//CTQ2014-59832-JIN/ES/ESCANEO COMPUTACIONAL DE RELACIONES ESTRUCTURA%2FACTIVIDAD DE CATALIZADORES DE OXIDACION DEL AGUA PARA LA GENERACION DE H2/ info:eu-repo/grantAgreement/EC/FP7/293900/EU/Ab initio Statics and Molecular Dynamics Simulation of Olefin Metathesis Catalysts for pharmacological purposes/COMPUTEDRUG |
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| Attribution 4.0 Spain | |
| http://creativecommons.org/licenses/by/4.0/es/ | |
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Metàtesi (Química)
Metathesis (Chemistry) Polimerització Polymerization Catalitzadors Catalysts |
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| Simple activation by acid of latent Ru-NHC-based metathesis initiators bearing 8-quinolinolate co-ligands | |
| info:eu-repo/semantics/article | |
| DUGiDocs |
