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Stereospecific C-H oxidation with H2O2 catalyzed by a chemically robust site-isolated iron catalyst

Check for cavities: An exceptionally active nonheme iron catalyst employs H2O2 as an oxidant for the stereospecific hydroxylation of alkanes (see scheme). The iron site is located in a chemically robust cavity made up by the ligands

Aquest mateix article està publicat a l’edició alemanya d’’Angewandte Chemie’ (ISSN 0044-8249, EISSN 1521-3757), 2009, vol.121, núm. 31, p. 5830–5833. DOI http://dx.doi.org/10.1002/ange.200901865

Financial support was provided by MCYT of Spain through projects CTQ2006-05367/BQU to M.C. L.G., A.C., and I.G.B. thank MICINN for PhD grants

© Angewandte Chemie International Edition, 2009, vol. 48, núm. 31, p. 5720-5723

Wiley

Author: Gómez Martín, Laura
Garcia Bosch, Isaac
Company Casadevall, Anna
Benet Buchholz, Jordi
Polo Ortiz, Alfonso
Sala Román, Xavier
Ribas Salamaña, Xavi
Costas Salgueiro, Miquel
Date: 2009 July 20
Abstract: Check for cavities: An exceptionally active nonheme iron catalyst employs H2O2 as an oxidant for the stereospecific hydroxylation of alkanes (see scheme). The iron site is located in a chemically robust cavity made up by the ligands
Aquest mateix article està publicat a l’edició alemanya d’’Angewandte Chemie’ (ISSN 0044-8249, EISSN 1521-3757), 2009, vol.121, núm. 31, p. 5830–5833. DOI http://dx.doi.org/10.1002/ange.200901865
Financial support was provided by MCYT of Spain through projects CTQ2006-05367/BQU to M.C. L.G., A.C., and I.G.B. thank MICINN for PhD grants
Format: application/pdf
ISSN: 1433-7851 (versió paper)
1521-3773 (versió electrònica)
Document access: http://hdl.handle.net/10256/13478
Language: eng
Publisher: Wiley
Collection: MEC/PN 2006-2009/ CTQ2006- 05367/BQU
Reproducció digital del document publicat a: http://dx.doi.org/10.1002/anie.200901865
Articles publicats (D-Q)
Is part of: © Angewandte Chemie International Edition, 2009, vol. 48, núm. 31, p. 5720-5723
Rights: Tots els drets reservats
Subject: Oxidació
Oxidation
Catàlisi homogènia
Homogeneous catalysis
Title: Stereospecific C-H oxidation with H2O2 catalyzed by a chemically robust site-isolated iron catalyst
Type: info:eu-repo/semantics/article
Repository: DUGiDocs

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