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Triplet-triplet energy transfer in DNA: A process that occurs on the nanosecond timescale

Aquest mateix article està publicat a l’edició alemanya d’’Angewandte Chemie’ (ISSN 0044-8249, EISSN 1521-3757), 2011, vol.123, núm. 8, p. 1860–1862. DOI http://dx.doi.org/10.1002/ange.201004732

No will to wander: Triplet-triplet electronic energy transfer in polyA-polyT DNA sequences was studied by using semiempirical quantum-chemical methods coupled to classical molecular-dynamics simulations. Triplet excited states in DNA were found to be almost completely localized on single nucleobases; the characteristic time for their migration along the A-A and T-T stacks was found to be 0.8 and 6.4ns

C.C. acknowledges support from the Departament d’Innovaci , Universitats i Empresa of the Generalitat de Catalunya (grant no. 2008BPB00108). A.A.V. is grateful to the Spanish Ministry of Education and Science for financial support (project CTQ2009-12346)

Wiley

Director: Ministerio de Ciencia e Innovación (Espanya)
Autor: Curutchet, Carles
Voityuk, Alexander A.
Resum: Aquest mateix article està publicat a l’edició alemanya d’’Angewandte Chemie’ (ISSN 0044-8249, EISSN 1521-3757), 2011, vol.123, núm. 8, p. 1860–1862. DOI http://dx.doi.org/10.1002/ange.201004732
No will to wander: Triplet-triplet electronic energy transfer in polyA-polyT DNA sequences was studied by using semiempirical quantum-chemical methods coupled to classical molecular-dynamics simulations. Triplet excited states in DNA were found to be almost completely localized on single nucleobases; the characteristic time for their migration along the A-A and T-T stacks was found to be 0.8 and 6.4ns
C.C. acknowledges support from the Departament d’Innovaci , Universitats i Empresa of the Generalitat de Catalunya (grant no. 2008BPB00108). A.A.V. is grateful to the Spanish Ministry of Education and Science for financial support (project CTQ2009-12346)
Format: application/pdf
Accés al document: http://hdl.handle.net/10256/13479
Llenguatge: eng
Editor: Wiley
Col·lecció: info:eu-repo/semantics/altIdentifier/doi/10.1002/anie.201004732
info:eu-repo/semantics/altIdentifier/issn/1433-7851
info:eu-repo/semantics/altIdentifier/eissn/1521-3773
MICINN/PN 2008-2010/ CTQ2009-12346
Drets: Tots els drets reservats
Matèria: ADN
DNA
Dinàmica molecular
Molecular dynamics
Transferència de càrrega
Charge transfer
Títol: Triplet-triplet energy transfer in DNA: A process that occurs on the nanosecond timescale
Tipus: info:eu-repo/semantics/article
Repositori: DUGiDocs

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