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Torres Antón, Òscar
Roglans i Ribas, Anna Pla i Quintana, Anna |
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2016 November 17 | |
N-Tosylhydrazone-yne-ene substrates are satisfactorily prepared and their cyclization under rhodium catalysis is evaluated. A cascade process involving rhodium vinyl carbene formation – through carbene/alkyne metathesis – and cyclopropanation has been developed to stereoselectively afford vinylcyclopropanes We are grateful for the financial support by the Spanish Ministry of Education and Science (MINECO) (Project CTQ2014-54306-P) and the DIUE of the Generalitat de Catalunya (Project 2014-SGR-931 and FI predoctoral grant to >.T.) |
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application/pdf | |
1615-4150 (versió paper) 1615-4169 (versió electrònica) |
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http://hdl.handle.net/10256/13483 | |
eng | |
Wiley | |
MINECO/PE 2015-2017/CTQ2014-54306-P Reproducció digital del document publicat a: http://dx.doi.org/10.1002/adsc.201600789 Articles publicats (D-Q) |
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© Advanced Synthesis and Catalysis, 2016, vol. 358, núm. 22, p. 3512-3516 | |
Tots els drets reservats | |
Ciclització (QuÃmica)
Ring formation (Chemistry) Carbens Carbenes (Methylene compounds) Ciclopropà Cyclopropane Catà lisi asimètrica Enantioselective catalysis Rodi Rhodium |
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An Enantioselective Cascade Cyclopropanation Reaction Catalyzed by Rhodium(I): Asymmetric Synthesis of Vinylcyclopropanes | |
info:eu-repo/semantics/article | |
DUGiDocs |