Ítem
|
Torres Antón, Òscar
Roglans i Ribas, Anna Pla i Quintana, Anna |
|
| 17 novembre 2016 | |
|
N-Tosylhydrazone-yne-ene substrates are satisfactorily prepared and their cyclization under rhodium catalysis is evaluated. A cascade process involving rhodium vinyl carbene formation – through carbene/alkyne metathesis – and cyclopropanation has been developed to stereoselectively afford vinylcyclopropanes We are grateful for the financial support by the Spanish Ministry of Education and Science (MINECO) (Project CTQ2014-54306-P) and the DIUE of the Generalitat de Catalunya (Project 2014-SGR-931 and FI predoctoral grant to >.T.) |
|
| application/pdf | |
|
1615-4150 (versió paper) 1615-4169 (versió electrònica) |
|
| http://hdl.handle.net/10256/13483 | |
| eng | |
| Wiley | |
|
MINECO/PE 2015-2017/CTQ2014-54306-P Reproducció digital del document publicat a: http://dx.doi.org/10.1002/adsc.201600789 Articles publicats (D-Q) |
|
| © Advanced Synthesis and Catalysis, 2016, vol. 358, núm. 22, p. 3512-3516 | |
| Tots els drets reservats | |
|
Ciclització (Química)
Ring formation (Chemistry) Carbens Carbenes (Methylene compounds) Ciclopropà Cyclopropane Catàlisi asimètrica Enantioselective catalysis Rodi Rhodium |
|
| An Enantioselective Cascade Cyclopropanation Reaction Catalyzed by Rhodium(I): Asymmetric Synthesis of Vinylcyclopropanes | |
| info:eu-repo/semantics/article | |
| DUGiDocs |
