Item


Biologically Inspired C−H and C=C Oxidations with Hydrogen Peroxide Catalyzed by Iron Coordination Complexes

The development of catalysts for the selective oxidation of readily available hydrocarbons or organic precursors into oxygenated products is a long-standing goal in organic synthesis. In the last decade, some iron coordination complexes have shown the potential to fit this role. These catalysts can mimic the O−O activation mode of far more sophisticated iron oxygenase enzymes, generating powerful yet selective oxidants. In this review, we report state-of-the-art C−H and C=C oxidations catalyzed by non-heme iron complexes and H2O2 as the oxidant. Finally, we briefly describe some novel oxidative reactivity and the perspectives of this chemistry

We acknowledge financial support from the Ministry of Economy and Competitiveness (MINECO) of Spain and Fondo Europeo de Desarrollo Regional (CTQ2015-70795-P/BQU), Consolider-Ingenio (CSD2010-00065), and the Catalan Department for Innovation, Universities and Enterprise (DIUE) of the Generalitat de Catalunya (2009SGR637)

© Chemistry - An Asian Journal, 2016, vol. 11, núm. 22, p. 3148-3158

Wiley

Author: Olivo, Giorgio
Cussó Forest, Olaf
Costas Salgueiro, Miquel
Date: 2016 November 22
Abstract: The development of catalysts for the selective oxidation of readily available hydrocarbons or organic precursors into oxygenated products is a long-standing goal in organic synthesis. In the last decade, some iron coordination complexes have shown the potential to fit this role. These catalysts can mimic the O−O activation mode of far more sophisticated iron oxygenase enzymes, generating powerful yet selective oxidants. In this review, we report state-of-the-art C−H and C=C oxidations catalyzed by non-heme iron complexes and H2O2 as the oxidant. Finally, we briefly describe some novel oxidative reactivity and the perspectives of this chemistry
We acknowledge financial support from the Ministry of Economy and Competitiveness (MINECO) of Spain and Fondo Europeo de Desarrollo Regional (CTQ2015-70795-P/BQU), Consolider-Ingenio (CSD2010-00065), and the Catalan Department for Innovation, Universities and Enterprise (DIUE) of the Generalitat de Catalunya (2009SGR637)
Format: application/pdf
ISSN: 1861-4728 (versió paper)
1861-471X (versió electrònica)
Document access: http://hdl.handle.net/10256/13494
Language: eng
Publisher: Wiley
Collection: MINECO/PE 2016-2018/CTQ2015-70795-P
Reproducció digital del document publicat a: http://dx.doi.org/10.1002/asia.201601170
Articles publicats (D-Q)
Is part of: © Chemistry - An Asian Journal, 2016, vol. 11, núm. 22, p. 3148-3158
Rights: Tots els drets reservats
Subject: Activació (Química)
Activation (Chemistry)
Oxidació
Oxidation
Catalitzadors
Catalysts
Title: Biologically Inspired C−H and C=C Oxidations with Hydrogen Peroxide Catalyzed by Iron Coordination Complexes
Type: info:eu-repo/semantics/article
Repository: DUGiDocs

Subjects

Authors