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M-Carboranylphosphinate as Versatile Building Blocks to Design all Inorganic Coordination Polymers

The first examples of coordination polymers of manganese(II) and a nickel(II) complex with a purely inorganic carboranylphosphinate ligand are reported, together with its exhaustive characterization. X-ray analysis revealed 1D polymeric chains with carboranylphosphinate ligands bridging two manganese(II) centers. The reactivity of polymer 1 with water and Lewis bases has also been studied

Thanks to MINECO (CTQ2015-66143-P, CTQ2010-16237 and SEV-2015-0496), Generalitat de Catalunya (2014/SGR/149), and COST CM1302. E.O. who is enrolled in the PhD program of the UAB thanks for FPU grant

American Chemical Society (ACS)

Manager: Ministerio de Economía y Competitividad (Espanya)
Author: Oleshkevich, Elena
Viñas, Clara
Romero García, Isabel
Choquesillo-Lazarte, Duane
Haukka, Matti
Teixidor Bombardó, Francesc
Abstract: The first examples of coordination polymers of manganese(II) and a nickel(II) complex with a purely inorganic carboranylphosphinate ligand are reported, together with its exhaustive characterization. X-ray analysis revealed 1D polymeric chains with carboranylphosphinate ligands bridging two manganese(II) centers. The reactivity of polymer 1 with water and Lewis bases has also been studied
Thanks to MINECO (CTQ2015-66143-P, CTQ2010-16237 and SEV-2015-0496), Generalitat de Catalunya (2014/SGR/149), and COST CM1302. E.O. who is enrolled in the PhD program of the UAB thanks for FPU grant
Format: application/pdf
Document access: http://hdl.handle.net/10256/14264
Language: eng
Publisher: American Chemical Society (ACS)
Collection: info:eu-repo/semantics/altIdentifier/doi/10.1021/acs.inorgchem.7b00610
info:eu-repo/semantics/altIdentifier/issn/0020-1669
info:eu-repo/semantics/altIdentifier/eissn/1520-510X
info:eu-repo/grantAgreement/MINECO//CTQ2015-66143-P/ES/COMPLEJOS FUNCIONALES PARA PROCESOS CATALITICOS SOSTENIBLES Y RESPETUOSOS CON EL MEDIO AMBIENTE/
Rights: Tots els drets reservats
Subject: Manganès -- Compostos
Manganese compounds
Química inorgànica
Chemistry, Inorganic
Title: M-Carboranylphosphinate as Versatile Building Blocks to Design all Inorganic Coordination Polymers
Type: info:eu-repo/semantics/article
Repository: DUGiDocs

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