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M-Carboranylphosphinate as Versatile Building Blocks to Design all Inorganic Coordination Polymers

The first examples of coordination polymers of manganese(II) and a nickel(II) complex with a purely inorganic carboranylphosphinate ligand are reported, together with its exhaustive characterization. X-ray analysis revealed 1D polymeric chains with carboranylphosphinate ligands bridging two manganese(II) centers. The reactivity of polymer 1 with water and Lewis bases has also been studied

Thanks to MINECO (CTQ2015-66143-P, CTQ2010-16237 and SEV-2015-0496), Generalitat de Catalunya (2014/SGR/149), and COST CM1302. E.O. who is enrolled in the PhD program of the UAB thanks for FPU grant

© Inorganic Chemistry, 2017, vol. 56, núm. 10, p. 5502-5505

American Chemical Society (ACS)

Manager: Ministerio de Economía y Competitividad (Espanya)
Author: Oleshkevich, Elena
Viñas, Clara
Romero García, Isabel
Choquesillo-Lazarte, Duane
Haukka, Matti
Teixidor Bombardó, Francesc
Date: 2017 May 25
Abstract: The first examples of coordination polymers of manganese(II) and a nickel(II) complex with a purely inorganic carboranylphosphinate ligand are reported, together with its exhaustive characterization. X-ray analysis revealed 1D polymeric chains with carboranylphosphinate ligands bridging two manganese(II) centers. The reactivity of polymer 1 with water and Lewis bases has also been studied
Thanks to MINECO (CTQ2015-66143-P, CTQ2010-16237 and SEV-2015-0496), Generalitat de Catalunya (2014/SGR/149), and COST CM1302. E.O. who is enrolled in the PhD program of the UAB thanks for FPU grant
Format: application/pdf
ISSN: 0020-1669 (versió paper)
1520-510X (versió electrònica)
Document access: http://hdl.handle.net/10256/14264
Language: eng
Publisher: American Chemical Society (ACS)
Collection: MINECO/PE 2016-2018/CTQ2015-66143-P
Reproducció digital del document publicat a: http://dx.doi.org/10.1021/acs.inorgchem.7b00610
Articles publicats (D-Q)
Is part of: © Inorganic Chemistry, 2017, vol. 56, núm. 10, p. 5502-5505
Rights: Tots els drets reservats
Subject: Manganès -- Compostos
Manganese compounds
Química inorgànica
Chemistry, Inorganic
Title: M-Carboranylphosphinate as Versatile Building Blocks to Design all Inorganic Coordination Polymers
Type: info:eu-repo/semantics/article
Repository: DUGiDocs

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