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Rapid degradation of azo-dye using Mn–Al powders produced by ball-milling

This study was conducted on the reduction reaction of the azo dye Reactive Black 5 by means of the Mn85Al15 particles prepared by melt-spinning and ball-milling processes. The morphology, the surface elementary composition and the phase structure of the powders were characterized by scanning electron microscopy, energy dispersive X-ray spectroscopy and X-ray diffraction. The degradation efficiency of the ball milled powder was measured by using an ultraviolet-visible absorption spectrophotometer and the collected powder was analyzed by means of Fourier transform infrared spectroscopy technique to characterize the functional groups in the extract. The degradation of Reactive Black 5 and the analysis of the aromatic by-products were investigated by high performance liquid chromatography coupled with tandem mass spectrometry. The ball-milled powder shows higher degradation efficiency and the Reactive Black 5 solution was completely decolorized after 30 min. The degradation kinetics and the formation by-products depend on the pH and temperature of the solution. The analyses of the extracted product confirmed the cleavage of the (–N[double bond, length as m-dash]N–) bonds. Our findings are expected to pave the way for a new opportunity with regard to the functional applications of nanostructured metallic particles

Royal Society of Chemistry (RSC)

Author: Ben Mbarek, Wael
Azabou, Myriam
Pineda, Eloi
Fiol Santaló, Núria
Escoda i Acero, Ma. Lluïsa
Suñol Martínez, Joan Josep
Khitouni, Mohamed
Date: 2017 February 22
Abstract: This study was conducted on the reduction reaction of the azo dye Reactive Black 5 by means of the Mn85Al15 particles prepared by melt-spinning and ball-milling processes. The morphology, the surface elementary composition and the phase structure of the powders were characterized by scanning electron microscopy, energy dispersive X-ray spectroscopy and X-ray diffraction. The degradation efficiency of the ball milled powder was measured by using an ultraviolet-visible absorption spectrophotometer and the collected powder was analyzed by means of Fourier transform infrared spectroscopy technique to characterize the functional groups in the extract. The degradation of Reactive Black 5 and the analysis of the aromatic by-products were investigated by high performance liquid chromatography coupled with tandem mass spectrometry. The ball-milled powder shows higher degradation efficiency and the Reactive Black 5 solution was completely decolorized after 30 min. The degradation kinetics and the formation by-products depend on the pH and temperature of the solution. The analyses of the extracted product confirmed the cleavage of the (–N[double bond, length as m-dash]N–) bonds. Our findings are expected to pave the way for a new opportunity with regard to the functional applications of nanostructured metallic particles
Format: application/pdf
Document access: http://hdl.handle.net/10256/14608
Language: eng
Publisher: Royal Society of Chemistry (RSC)
Collection: info:eu-repo/semantics/altIdentifier/doi/10.1039/C6RA28578C
info:eu-repo/semantics/altIdentifier/issn/2046-2069
Rights: Attribution-NonCommercial 3.0 Spain
Rights URI: http://creativecommons.org/licenses/by-nc/3.0/es/
Subject: Colorants azoics
Azo dyes
Title: Rapid degradation of azo-dye using Mn–Al powders produced by ball-milling
Type: info:eu-repo/semantics/article
Repository: DUGiDocs

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