Item
| Agencia Estatal de Investigación | |
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Zghal, Imen
Farjas Silva, Jordi Camps Soler, Jaume Dammak, Mohamed Roura Grabulosa, Pere |
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| 2020 January 1 | |
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Thermal decomposition of cerium triethanolamine complexes to cerium oxide, CeO2, in inert and oxidative atmospheres is investigated by thermogravimetry combined with infrared evolved gas analysis and the main volatiles formed during thermal decomposition are identified. Intermediate and final products are characterized by infrared spectroscopy, X-Ray diffraction and elemental analysis. Several overlapping steps occurring along the decomposition path are identified and plausible reaction pathways are presented. It will be shown that, independent of the atmosphere, decomposition starts around 200 °C but the endset temperature depends on the composition of the gas, i.e., the more inert the atmosphere, the higher the endset temperature. Finally, the effect the temperature and amount of triethanolamine used have during compound synthesis is discussed This work was funded by Ministerio de Ciencia, Innovación y Universidades (grant number RTI2018-095853-B-C22), by the Generalitat of Catalunya (2017-SGR-1519) and by the Universitat de Girona (UdG, contract number MPCUdG2016/059) |
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| application/pdf | |
| http://hdl.handle.net/10256/17132 | |
| eng | |
| Elsevier | |
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info:eu-repo/semantics/altIdentifier/doi/10.1016/j.tca.2019.178430 info:eu-repo/semantics/altIdentifier/issn/0040-6031 info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación CientÃfica y Técnica y de Innovación 2017-2020/RTI2018-095853-B-C22/ES/ANALISIS TERMICO PARA EL CRECIMIENTO DE CINTAS GRUESAS SUPERCONDUCTORAS DE REBA2CU3O7-X/ |
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| Reconeixement-NoComercial-SenseObraDerivada 4.0 Internacional | |
| http://creativecommons.org/licenses/by-nc-nd/4.0 | |
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Anà lisi tèrmica
Thermal analysis Trietanolamina Triethanolamine Piròlisi Pyrolysis |
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| Thermal decomposition of cerium triethanolamine complexes | |
| info:eu-repo/semantics/article | |
| DUGiDocs |
