DUGi: Ítem | DUGiDocs - The cycloaddition chemistry of 3-oxidopyraziniums. Dimerisation of 1-(4-methoxybenzyl)-5,6-dimethyl-3-oxidopyrazinium

Ítem

Autor:	Riesco-Llach, Gerard Planas i Grabuleda, Marta Feliu Soley, Lidia Joule, John A.
Data:	12 juny 2024
Resum:	3-Oxidopyraziniums are accessed from 2(1H)-pyrazinones via N-alkylation and then exposure of the resulting pyrazinium salts to mild base at room temperature. 3-Oxidopyraziniums react with acrylates in a 1,3-dipolar cyclisation producing 3,8-diazabicyclo[3.2.1]octanes. 1-(4-methoxybenzyl)-5,6-dimethyl-3-oxidopyrazinium (C14H16N2O2) dimerises at room temperature, forming a tetracyclic alcohol C28H34N4O5, the structure of which was elucidated using spectroscopic and X-ray analyses
Format:	application/pdf
Accés al document:	http://hdl.handle.net/10256/25171
Llenguatge:	eng
Editor:	ARKAT USA, Inc.
Col·lecció:	info:eu-repo/semantics/altIdentifier/doi/10.24820/ark.5550190.p012.217 info:eu-repo/semantics/altIdentifier/issn/1551-7004 info:eu-repo/semantics/altIdentifier/eissn/1551-7012
Drets:	Reconeixement 4.0 Internacional
URI Drets:	http://creativecommons.org/licenses/by/4.0
Matèria:	Reaccions d’addició Ciclització (Química) Compostos orgànics Addition reactions Ring formation (Chemistry) Organic compounds
Títol:	The cycloaddition chemistry of 3-oxidopyraziniums. Dimerisation of 1-(4-methoxybenzyl)-5,6-dimethyl-3-oxidopyrazinium
Tipus:	info:eu-repo/semantics/article
Repositori:	DUGiDocs