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Iron-Catalyzed C-H Hydroxylation and Olefin cis-Dihydroxylation Using a Single-Electron Oxidant and Water as the Oxygen-Atom Source

Bioinspired oxidation: the hydroxylation of alkanes with retention of the configuration and the cis-dihydroxylation of olefins can be accomplished using [FeII(CF3SO3)2(Me,HPyTACN)] as a catalyst, water as an oxygen-atom source, and cerium ammonium nitrate (CAN) as a single-electron oxidant. The oxidation of CH bonds and CC bonds, as well as water oxidation involves a common reaction intermediate formed by the reaction of CAN and [FeIV(O)(OH2)(Me,HPyTACN)]+

Financial support by MCYT (CTQ2009-08864, and Consolider Ingenio CSD-2010-00065). European Research Council project ERC-2009-StG-239910. JLF thanks MICINN for a RyC contract. ICREA Academia Awards and SGR-239910

Wiley-VCH Verlag Berlin

Manager: Ministerio de Ciencia e Innovación (Espanya)
Ministerio de Ciencia y Tecnología (Espanya)
Author: Garcia Bosch, Isaac
Codolà Duch, Zoel
Prat Casellas, Irene
Ribas Salamaña, Xavi
Lloret Fillol, Julio
Costas Salgueiro, Miquel
Date: 2012
Abstract: Bioinspired oxidation: the hydroxylation of alkanes with retention of the configuration and the cis-dihydroxylation of olefins can be accomplished using [FeII(CF3SO3)2(Me,HPyTACN)] as a catalyst, water as an oxygen-atom source, and cerium ammonium nitrate (CAN) as a single-electron oxidant. The oxidation of CH bonds and CC bonds, as well as water oxidation involves a common reaction intermediate formed by the reaction of CAN and [FeIV(O)(OH2)(Me,HPyTACN)]+
Financial support by MCYT (CTQ2009-08864, and Consolider Ingenio CSD-2010-00065). European Research Council project ERC-2009-StG-239910. JLF thanks MICINN for a RyC contract. ICREA Academia Awards and SGR-239910
Format: application/pdf
Document access: http://hdl.handle.net/10256/7297
Language: eng
Publisher: Wiley-VCH Verlag Berlin
Collection: info:eu-repo/semantics/altIdentifier/doi/10.1002/chem.201202147
info:eu-repo/semantics/altIdentifier/issn/0947-6539
info:eu-repo/semantics/altIdentifier/eissn/1521-3765
MICYT/CTQ2009-08864
MICINN/PN 2010-2016/CSD2010-00065
info:eu-repo/grantAgreement/EC/FP7/239910/EU/Bio-inspired Design of Catalysts for Selective Oxidations of C-H and C=C Bonds/BIDECASEOX
Rights: Tots els drets reservats
Subject: Química bioinorgànica
Bioinorganic chemistry
Activació (Química)
Activation (Chemistry)
Compostos organometàl·lics
Organometallic compounds
Oxidació
Oxidation
Title: Iron-Catalyzed C-H Hydroxylation and Olefin cis-Dihydroxylation Using a Single-Electron Oxidant and Water as the Oxygen-Atom Source
Type: info:eu-repo/semantics/article
Repository: DUGiDocs

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