Ítem
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Martí, Josep
Bishop, David M. |
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| Two common methods of accounting for electric-field-induced perturbations to molecular vibration are analyzed and compared. The first method is based on a perturbation-theoretic treatment and the second on a finite-field treatment. The relationship between the two, which is not immediately apparent, is made by developing an algebraic formalism for the latter. Some of the higher-order terms in this development are documented here for the first time. As well as considering vibrational dipole polarizabilities and hyperpolarizabilities, we also make mention of the vibrational Stark effec | |
| http://hdl.handle.net/2072/116581 | |
| eng | |
| American Institute of Physics | |
| Tots els drets reservats | |
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Camps elèctrics
Molècules Moments dipolars Pertorbació (Matemàtica) Polarització (Electricitat) Electric fields Molecules Perturbation (Mathematics) Polarization (Electricity) |
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| A comparative analysis of two methods for the calculation of electric-field-induced perturbations to molecular vibration | |
| info:eu-repo/semantics/article | |
| Recercat |
