DUGi: Ítem | Recercat - Evidence that steric factors modulate reactivity of tautomeric iron-oxo species in stereospecific alkane C-H hydroxylation

Ítem

Autor:	Mitra, Mainak Lloret Fillol, Julio Haukka, Matti Costas Salgueiro, Miquel Nordlander, Ebbe
Resum:	A new iron complex mediates stereospecific hydroxylation of alkyl C-H bonds with hydrogen peroxide, exhibiting excellent efficiency. Isotope labelling studies provide evidence that the relative reactivity of tautomerically related oxo-iron species responsible for the C-H hydroxylation reaction is dominated by steric factors This work has been supported by the European Union (the Erasmus Mundus program), the International Research Training Group Metal Sites in Biomolecules: Structures, Regulation and Mechanisms (www.biometals.eu), and COST Action CM1003. M.C. acknowledges ERC-29910, MINECO of Spain for CTQ2012- 37420-C02-01/BQU and CSD2010-00065, catalan DIUE (2009SGR637) and an ICREA academia award. J.Ll. thanks MICINN for a RyC contract
Accés al document:	http://hdl.handle.net/2072/258427
Llenguatge:	eng
Editor:	Royal Society of Chemistry (RSC)
Drets:	Attribution-NonCommercial 3.0 Spain
URI Drets:	http://creativecommons.org/licenses/by-nc/3.0/es/
Matèria:	Oxidació Oxidation Ferro -- Compostos Iron compounds Catàlisi Catalysis
Títol:	Evidence that steric factors modulate reactivity of tautomeric iron-oxo species in stereospecific alkane C-H hydroxylation
Tipus:	info:eu-repo/semantics/article
Repositori:	Recercat