Ítem
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Ministerio de Ciencia e Innovación (Espanya)
Generalitat de Catalunya. Agència de Gestió d’Ajuts Universitaris i de Recerca |
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Broggi, Julie
Jurcik, Vaclav Songis, Olivier Poater Teixidor, Albert Cavallo, Luigi Slawin, Alexandra M. Z. Cazin, Catherine S. J. |
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The [Pd(SIPr)(PCy3)] complex efficiently promotes a tandem process involving dehydrogenation of formic acid and hydrogenation of C-C multiple bonds using H-2 formed in situ. The isolation of a key catalytic hydridoformatopalladium species, [Pd{OC(O)H}(H)(IPr)(PCy3)], is reported. The complex plays a key role in the Pd(0)-mediated formation of hydrogen from formic acid. Mechanistic and computational studies delineate the operational role of the palladium complex in this efficient tandem sequence The EPSRC and the Royal Society (University Research Fellowship to C.S.J.C.), the Spanish MICINN (Ramon y Cajal Contract RYC-2009-05226 to A.P.), the EC (Career Integration Grant CIG09-GA-2011-293900 to A.P.), and Generalitat de Catalunya (BE Fellowship 2011BE100793 to A.P.) are acknowledged for financial support |
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| http://hdl.handle.net/2072/294972 | |
| eng | |
| American Chemical Society | |
| Tots els drets reservats | |
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Compostos heterocíclics
Heterocyclic compounds Catàlisi Catalysis |
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| The Isolation of [Pd{OC(O)H}(H)(NHC)(PR3)] (NHC = N-Heterocyclic Carbene) and Its Role in Alkene and Alkyne Reductions Using Formic Acid | |
| info:eu-repo/semantics/article | |
| Recercat |
