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Highly stereoselective epoxidation with H2O2 catalyzed by electron-rich aminopyridine manganese catalysts

Fast, efficient, and highly stereoselective epoxidation with H 2O2 is reached by manganese coordination complexes with e-rich aminopyridine tetradentate ligands. It is shown that the electronic properties of these catalysts vary systematically with the stereoselectivity of the O-atom transfer event and exert fine control over the activation of hydrogen peroxide, reducing the amount of carboxylic acid co-catalyst necessary for efficient operation

American Chemical Society (ACS)

Director: European Research Council
Ministerio de Economía y Competitividad (Espanya)
Generalitat de Catalunya. Agència de Gestió d’Ajuts Universitaris i de Recerca
Ministerio de Ciencia e Innovación (Espanya)
Autor: Cussó Forest, Olaf
Garcia Bosch, Isaac
Font Gimbernat, David
Ribas Salamaña, Xavi
Lloret Fillol, Julio
Costas Salgueiro, Miquel
Resum: Fast, efficient, and highly stereoselective epoxidation with H 2O2 is reached by manganese coordination complexes with e-rich aminopyridine tetradentate ligands. It is shown that the electronic properties of these catalysts vary systematically with the stereoselectivity of the O-atom transfer event and exert fine control over the activation of hydrogen peroxide, reducing the amount of carboxylic acid co-catalyst necessary for efficient operation
Accés al document: http://hdl.handle.net/2072/295531
Llenguatge: eng
Editor: American Chemical Society (ACS)
Drets: Tots els drets reservats
Matèria: Epòxids
Epoxy compounds
Compostos heterocíclics
Heterocyclic compounds
Catalitzadors
Catalysts
Títol: Highly stereoselective epoxidation with H2O2 catalyzed by electron-rich aminopyridine manganese catalysts
Tipus: info:eu-repo/semantics/article
Repositori: Recercat

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