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Ministerio de Ciencia e Innovación (Espanya)
Generalitat de Catalunya. Agència de Gestió d’Ajuts Universitaris i de Recerca |
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Garcia Borrà s, Marc
Osuna Oliveras, SÃlvia Swart, Marcel Luis Luis, Josep Maria Solà i Puig, Miquel |
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In this work we show that the regioselectivity of the Diels-Alder, 1,3-dipolar, and carbene cycloadditions to C60 changes from the usual [6,6] addition in neutral species to the [5,6] attack when the number of electrons added to the fullerenic cage increases. Changes in the aromaticity of the five- and six-membered rings of C60 during the reduction process provide a rationale to understand this regioselectivity change | |
http://hdl.handle.net/2072/295562 | |
eng | |
Royal Society of Chemistry (RSC) | |
Tots els drets reservats | |
Diels-Alder, Reacció de
Diels-Alder reaction Reaccions quÃmiques regioselectives Regioselectivity Chemical reactions Fullerenes Ful·lerens Aromaticitat (QuÃmica) Aromaticity (Chemistry) |
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Electrochemical control of the regioselectivity in the exohedral functionalization of C60: The role of aromaticity | |
info:eu-repo/semantics/article | |
Recercat |