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A simple catalytic system based on PdCl2 (CH3CN) 2 in water for cross-coupling reactions using diazonium salts

Aryl-heteroaryl and heteroaryl-heteroaryl compounds are obtained through the Suzuki-Miyaura cross-coupling reactions between diazonium salts and potassium trifluoroborates using PdCl2(CH3CN)2 as the catalyst in water and in the absence of any additive, ligand or base. In addition, the same mild catalytic system is effective for the Matsuda-Heck reaction between several monoolefins with aryldiazonium salts

Financial support from MICINN (CTQ2011-23121) of Spain and ’Generalitat de Catalunya’ (2009SGR637) is acknowledged

Elsevier

Director: Ministerio de Ciencia e Innovación (Espanya)
Generalitat de Catalunya. Agència de Gestió d’Ajuts Universitaris i de Recerca
Autor: El Bakouri, Ouissam
Fernández Wang, Martí
Brun Massó, Sandra
Pla i Quintana, Anna
Roglans i Ribas, Anna
Resum: Aryl-heteroaryl and heteroaryl-heteroaryl compounds are obtained through the Suzuki-Miyaura cross-coupling reactions between diazonium salts and potassium trifluoroborates using PdCl2(CH3CN)2 as the catalyst in water and in the absence of any additive, ligand or base. In addition, the same mild catalytic system is effective for the Matsuda-Heck reaction between several monoolefins with aryldiazonium salts
Financial support from MICINN (CTQ2011-23121) of Spain and ’Generalitat de Catalunya’ (2009SGR637) is acknowledged
Accés al document: http://hdl.handle.net/2072/296584
Llenguatge: eng
Editor: Elsevier
Drets: Tots els drets reservats
Matèria: Reaccions químiques
Chemical reactions
Compost de diazoni
Diazonium compounds
Títol: A simple catalytic system based on PdCl2 (CH3CN) 2 in water for cross-coupling reactions using diazonium salts
Tipus: info:eu-repo/semantics/article
Repositori: Recercat

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