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Nickel (0) complexes of polyunsaturated azamacrocyclic ligands

A series of nickel(0) complexes, 3, 4, and 5, containing unsaturated 15-membered azamacrocyclic ligands have been synthesized. Structural characterization of the complexes is based on NMR spectroscopy, X-ray diffraction analysis, and differential scanning calorimetry. In addition, the catalytic activity of the complexes in the Suzuki-Miyaura cross-coupling of arylboronic acids and aryl halides has been tested

The project was funded by the program Acciones Integradas Hispano-Alemanas between Germany (DAAD, BMBF) and Spain (MICINN, Spanish Ministry of Science and Innovation, Project AIB2010DE-00262). Financial support from the MICINN (Projects CTQ2008-05409, CTQ2011-23121) and the Generalitat de Catalunya (Project 2009SGR637) is also gratefully acknowledged. S.B. thanks the University of Girona for a predoctoral grant

American Chemical Society (ACS)

Manager: Ministerio de Ciencia e Innovación (Espanya)
Ministerio de Educación y Ciencia (Espanya)
Generalitat de Catalunya. Agència de Gestió d’Ajuts Universitaris i de Recerca
Author: Brun Massó, Sandra
Pla i Quintana, Anna
Roglans i Ribas, Anna
Pörschke, Klaus Richard
Goddard, Richard
Abstract: A series of nickel(0) complexes, 3, 4, and 5, containing unsaturated 15-membered azamacrocyclic ligands have been synthesized. Structural characterization of the complexes is based on NMR spectroscopy, X-ray diffraction analysis, and differential scanning calorimetry. In addition, the catalytic activity of the complexes in the Suzuki-Miyaura cross-coupling of arylboronic acids and aryl halides has been tested
The project was funded by the program Acciones Integradas Hispano-Alemanas between Germany (DAAD, BMBF) and Spain (MICINN, Spanish Ministry of Science and Innovation, Project AIB2010DE-00262). Financial support from the MICINN (Projects CTQ2008-05409, CTQ2011-23121) and the Generalitat de Catalunya (Project 2009SGR637) is also gratefully acknowledged. S.B. thanks the University of Girona for a predoctoral grant
Document access: http://hdl.handle.net/2072/296589
Language: eng
Publisher: American Chemical Society (ACS)
Rights: Tots els drets reservats
Subject: Níquel -- Compostos
Nickel compounds
Metalls de transició -- Compostos
Transition metal compounds
Title: Nickel (0) complexes of polyunsaturated azamacrocyclic ligands
Type: info:eu-repo/semantics/article
Repository: Recercat

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