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Ministerio de EconomÃa y Competitividad (Espanya)
Generalitat de Catalunya. Agència de Gestió d’Ajuts Universitaris i de Recerca |
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Hassanpour, Azin
Acuña-Parés, Ferran Luis Luis, Josep Maria Cussó Forest, Olaf Morales de la Rosa, Silvia Campos-MartÃn, José Miguel Fierro, Jose L.G. Costas Salgueiro, Miquel Lloret Fillol, Julio Mas-Ballesté, Rubén |
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Herein we show that species generated upon reaction of α-[Fe(CF3SO3)2(BPMCN)] (BPMCN = N,N′-bis(2-pyridylmethyl)-trans-1,2-diaminocyclohexane) with H2O2 (putatively [FeV(O)(OH)(BPMCN)]) is able to efficiently oxidize H2 to H2O even in the presence of organic substrates, while species formed in the presence of acetic acid (putatively [FeV(O)(OAc)(BPMCN)]) prefer organic substrate oxidation over H2 activation. Mechanistic implications have been analysed with the aid of computational methods This work was supported by Spanish Ministerio de Economia y Competitividad (CTQ2012-37420-C02-02 and 01) European Research Council (StG 239910), and Generalitat de Catalunya (2014 SGR 862 and ICREA Academia award to MC). J.Ll.-F. thanks the CELLEX foundation for the starting career program for financial support |
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| http://hdl.handle.net/2072/297573 | |
| eng | |
| Royal Society of Chemistry (RSC) | |
| Tots els drets reservats | |
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Oxidació
Oxidation |
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| H2 oxidation versus organic substrate oxidation in non-heme iron mediated reactions with H2O2 | |
| info:eu-repo/semantics/article | |
| Recercat |
