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Simple and Sustainable Copper-O 2 Chemistry towards High-Value Products

Oxygen meets its end, or does it? Straightforward Cu-catalyzed preparation of α-ketoamides has been recently achieved through oxidative coupling of aryl acetaldehydes and arylamines by using O2 as the terminal oxidant. The work represents a remarkable example of a simple and sustainable transformation to yield elaborate and more complex biologically relevant oxidized products from readily available reagents under mild conditions

Anna Company and Xavi Ribas are acknowledged for a critical reading of this manuscript and valuable opinions. Financial support by ICREA-Academia Awards, Catalan SGR 2009-SGR637, MICINN-Spain (CTQ2009-08464/BQU), the European Research Foundation for the Project ERC-2009-StG-239910 and Consolider Ingenio/CSD2010-00065

Wiley-VCH Verlag

Manager: Ministerio de Ciencia e Innovación (Espanya)
Generalitat de Catalunya. Agència de Gestió d’Ajuts Universitaris i de Recerca
Author: Costas Salgueiro, Miquel
Abstract: Oxygen meets its end, or does it? Straightforward Cu-catalyzed preparation of α-ketoamides has been recently achieved through oxidative coupling of aryl acetaldehydes and arylamines by using O2 as the terminal oxidant. The work represents a remarkable example of a simple and sustainable transformation to yield elaborate and more complex biologically relevant oxidized products from readily available reagents under mild conditions
Anna Company and Xavi Ribas are acknowledged for a critical reading of this manuscript and valuable opinions. Financial support by ICREA-Academia Awards, Catalan SGR 2009-SGR637, MICINN-Spain (CTQ2009-08464/BQU), the European Research Foundation for the Project ERC-2009-StG-239910 and Consolider Ingenio/CSD2010-00065
Document access: http://hdl.handle.net/2072/297575
Language: eng
Publisher: Wiley-VCH Verlag
Rights: Tots els drets reservats
Subject: Synthetic methods
Activació (Química)
Activation (Chemistry)
Coure
Copper
Catàlisi
Catalysis
Title: Simple and Sustainable Copper-O 2 Chemistry towards High-Value Products
Type: info:eu-repo/semantics/article
Repository: Recercat

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