Ítem
| Ministerio de Economía y Competitividad (Espanya) | |
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Manzini, Simone
Cavallo, Luigi Nolan, Steven P. Urbina-Blanco, Cesar A. Nelson, David J. Poater Teixidor, Albert Lebl, Tomas Meiries, Sébastien Slawin, Alexandra M. Z. Falivene, Laura |
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The commercially-available metathesis pre-catalyst M23 has been evaluated alongside new complex [RuCl2((3-phenyl)indenylidene)(PPh3)(SIPrOMe)] (1), which bears a para-methoxy-substituted N-heterocyclic carbene ligand. Several model metathesis reactions could be conducted using only parts-per-million levels of ruthenium catalyst. The effects of the different NHC ligands on reactivity have been explored SPN thanks the European Research Council (227817) (Advanced Investigator Award ‘FUNCAT’), the EU (CP-FP 211468) (Seventh Framework Programme Project ‘EUMET’), and the Engineering and Physical Sciences Research Council for funding. SPN is a Royal Society Wolfson Merit Award holder. AP thanks the Spanish MINECO for a Ram on y Cajal contract (RYC-2009-05226) and European Commission for a Career Integration Grant (CIG09-GA-2011- 293900) |
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| http://hdl.handle.net/2072/298685 | |
| eng | |
| Elsevier | |
| Tots els drets reservats | |
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Funcional de densitat, Teoria del
Density functionals Metàtesi (Química) Metathesis (Chemistry) Ruteni Ruthenium Alquens Alkenes |
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| Evaluation of an olefin metathesis pre-catalyst with a bulky and electron-rich N-heterocyclic carbene | |
| info:eu-repo/semantics/article | |
| Recercat |
