Ítem
| Ministerio de Economía y Competitividad (Espanya) | |
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Torres Antón, Òscar
Roglans i Ribas, Anna Pla i Quintana, Anna |
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N-Tosylhydrazone-yne-ene substrates are satisfactorily prepared and their cyclization under rhodium catalysis is evaluated. A cascade process involving rhodium vinyl carbene formation – through carbene/alkyne metathesis – and cyclopropanation has been developed to stereoselectively afford vinylcyclopropanes We are grateful for the financial support by the Spanish Ministry of Education and Science (MINECO) (Project CTQ2014-54306-P) and the DIUE of the Generalitat de Catalunya (Project 2014-SGR-931 and FI predoctoral grant to >.T.) |
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| http://hdl.handle.net/2072/298898 | |
| eng | |
| Wiley | |
| Tots els drets reservats | |
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Ciclització (Química)
Ring formation (Chemistry) Carbens Carbenes (Methylene compounds) Ciclopropà Cyclopropane Catàlisi asimètrica Enantioselective catalysis Rodi Rhodium |
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| An Enantioselective Cascade Cyclopropanation Reaction Catalyzed by Rhodium(I): Asymmetric Synthesis of Vinylcyclopropanes | |
| info:eu-repo/semantics/article | |
| Recercat |
