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M-Carboranylphosphinate as Versatile Building Blocks to Design all Inorganic Coordination Polymers

The first examples of coordination polymers of manganese(II) and a nickel(II) complex with a purely inorganic carboranylphosphinate ligand are reported, together with its exhaustive characterization. X-ray analysis revealed 1D polymeric chains with carboranylphosphinate ligands bridging two manganese(II) centers. The reactivity of polymer 1 with water and Lewis bases has also been studied

Thanks to MINECO (CTQ2015-66143-P, CTQ2010-16237 and SEV-2015-0496), Generalitat de Catalunya (2014/SGR/149), and COST CM1302. E.O. who is enrolled in the PhD program of the UAB thanks for FPU grant

American Chemical Society (ACS)

Director: Ministerio de Economía y Competitividad (Espanya)
Autor: Oleshkevich, Elena
Viñas, Clara
Romero García, Isabel
Choquesillo-Lazarte, Duane
Haukka, Matti
Teixidor Bombardó, Francesc
Resum: The first examples of coordination polymers of manganese(II) and a nickel(II) complex with a purely inorganic carboranylphosphinate ligand are reported, together with its exhaustive characterization. X-ray analysis revealed 1D polymeric chains with carboranylphosphinate ligands bridging two manganese(II) centers. The reactivity of polymer 1 with water and Lewis bases has also been studied
Thanks to MINECO (CTQ2015-66143-P, CTQ2010-16237 and SEV-2015-0496), Generalitat de Catalunya (2014/SGR/149), and COST CM1302. E.O. who is enrolled in the PhD program of the UAB thanks for FPU grant
Accés al document: http://hdl.handle.net/2072/299724
Llenguatge: eng
Editor: American Chemical Society (ACS)
Drets: Tots els drets reservats
Matèria: Manganès -- Compostos
Manganese compounds
Química inorgànica
Chemistry, Inorganic
Títol: M-Carboranylphosphinate as Versatile Building Blocks to Design all Inorganic Coordination Polymers
Tipus: info:eu-repo/semantics/article
Repositori: Recercat

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