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DUGi: Ítem | Recercat - Iron-Catalyzed C-H Hydroxylation and Olefin cis-Dihydroxylation Using a Single-Electron Oxidant and Water as the Oxygen-Atom Source

Ítem


Iron-Catalyzed C-H Hydroxylation and Olefin cis-Dihydroxylation Using a Single-Electron Oxidant and Water as the Oxygen-Atom Source

Bioinspired oxidation: the hydroxylation of alkanes with retention of the configuration and the cis-dihydroxylation of olefins can be accomplished using [FeII(CF3SO3)2(Me,HPyTACN)] as a catalyst, water as an oxygen-atom source, and cerium ammonium nitrate (CAN) as a single-electron oxidant. The oxidation of CH bonds and CC bonds, as well as water oxidation involves a common reaction intermediate formed by the reaction of CAN and [FeIV(O)(OH2)(Me,HPyTACN)]+

Financial support by MCYT (CTQ2009-08864, and Consolider Ingenio CSD-2010-00065). European Research Council project ERC-2009-StG-239910. JLF thanks MICINN for a RyC contract. ICREA Academia Awards and SGR-239910

Wiley-VCH Verlag Berlin

Director: Ministerio de Ciencia e Innovación (Espanya)
Ministerio de Ciencia y Tecnología (Espanya)
Autor: Garcia Bosch, Isaac
Codolà Duch, Zoel
Prat Casellas, Irene
Ribas Salamaña, Xavi
Lloret Fillol, Julio
Costas Salgueiro, Miquel
Resum: Bioinspired oxidation: the hydroxylation of alkanes with retention of the configuration and the cis-dihydroxylation of olefins can be accomplished using [FeII(CF3SO3)2(Me,HPyTACN)] as a catalyst, water as an oxygen-atom source, and cerium ammonium nitrate (CAN) as a single-electron oxidant. The oxidation of CH bonds and CC bonds, as well as water oxidation involves a common reaction intermediate formed by the reaction of CAN and [FeIV(O)(OH2)(Me,HPyTACN)]+
Financial support by MCYT (CTQ2009-08864, and Consolider Ingenio CSD-2010-00065). European Research Council project ERC-2009-StG-239910. JLF thanks MICINN for a RyC contract. ICREA Academia Awards and SGR-239910
Accés al document: http://hdl.handle.net/2072/300404
Llenguatge: eng
Editor: Wiley-VCH Verlag Berlin
Drets: Tots els drets reservats
Matèria: Química bioinorgànica
Bioinorganic chemistry
Activació (Química)
Activation (Chemistry)
Compostos organometàl·lics
Organometallic compounds
Oxidació
Oxidation
Títol: Iron-Catalyzed C-H Hydroxylation and Olefin cis-Dihydroxylation Using a Single-Electron Oxidant and Water as the Oxygen-Atom Source
Tipus: info:eu-repo/semantics/article
Repositori: Recercat

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