Ítem
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Ministerio de Ciencia e Innovación (Espanya)
Ministerio de Ciencia y Tecnología (Espanya) |
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Garcia Bosch, Isaac
Codolà Duch, Zoel Prat Casellas, Irene Ribas Salamaña, Xavi Lloret Fillol, Julio Costas Salgueiro, Miquel |
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Bioinspired oxidation: the hydroxylation of alkanes with retention of the configuration and the cis-dihydroxylation of olefins can be accomplished using [FeII(CF3SO3)2(Me,HPyTACN)] as a catalyst, water as an oxygen-atom source, and cerium ammonium nitrate (CAN) as a single-electron oxidant. The oxidation of CH bonds and CC bonds, as well as water oxidation involves a common reaction intermediate formed by the reaction of CAN and [FeIV(O)(OH2)(Me,HPyTACN)]+ Financial support by MCYT (CTQ2009-08864, and Consolider Ingenio CSD-2010-00065). European Research Council project ERC-2009-StG-239910. JLF thanks MICINN for a RyC contract. ICREA Academia Awards and SGR-239910 |
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| http://hdl.handle.net/2072/300404 | |
| eng | |
| Wiley-VCH Verlag Berlin | |
| Tots els drets reservats | |
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Química bioinorgànica
Bioinorganic chemistry Activació (Química) Activation (Chemistry) Compostos organometàl·lics Organometallic compounds Oxidació Oxidation |
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| Iron-Catalyzed C-H Hydroxylation and Olefin cis-Dihydroxylation Using a Single-Electron Oxidant and Water as the Oxygen-Atom Source | |
| info:eu-repo/semantics/article | |
| Recercat |
