DUGi: Item | Recercat - Iron-Catalyzed C-H Hydroxylation and Olefin cis-Dihydroxylation Using a Single-Electron Oxidant and Water as the Oxygen-Atom Source

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Manager:	Ministerio de Ciencia e Innovación (Espanya) Ministerio de Ciencia y Tecnología (Espanya)
Author:	Garcia Bosch, Isaac Codolà Duch, Zoel Prat Casellas, Irene Ribas Salamaña, Xavi Lloret Fillol, Julio Costas Salgueiro, Miquel
Abstract:	Bioinspired oxidation: the hydroxylation of alkanes with retention of the configuration and the cis-dihydroxylation of olefins can be accomplished using [FeII(CF3SO3)2(Me,HPyTACN)] as a catalyst, water as an oxygen-atom source, and cerium ammonium nitrate (CAN) as a single-electron oxidant. The oxidation of CH bonds and CC bonds, as well as water oxidation involves a common reaction intermediate formed by the reaction of CAN and [FeIV(O)(OH2)(Me,HPyTACN)]+ Financial support by MCYT (CTQ2009-08864, and Consolider Ingenio CSD-2010-00065). European Research Council project ERC-2009-StG-239910. JLF thanks MICINN for a RyC contract. ICREA Academia Awards and SGR-239910
Document access:	http://hdl.handle.net/2072/300404
Language:	eng
Publisher:	Wiley-VCH Verlag Berlin
Rights:	Tots els drets reservats
Subject:	Química bioinorgànica Bioinorganic chemistry Activació (Química) Activation (Chemistry) Compostos organometàl·lics Organometallic compounds Oxidació Oxidation
Title:	Iron-Catalyzed C-H Hydroxylation and Olefin cis-Dihydroxylation Using a Single-Electron Oxidant and Water as the Oxygen-Atom Source
Type:	info:eu-repo/semantics/article
Repository:	Recercat