Ítem
| Ministerio de Economía y Competitividad (Espanya) | |
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Andris, Erik
Jašík, Juraj Gómez Martín, Laura Costas Salgueiro, Miquel Roithová, Jana |
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| 5 juny 2018 | |
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El mateix article està publicat a l’edició alemanya de la revista ’Angewandte chemie’ (issn 0044-8249, eissn 1521-3757), 2016, vol. 128, núm.11, p. 3701–3705. DOI http://dx.doi.org/10.1002/ange.201511374 Closely structurally related triplet and quintet iron(IV) oxo complexes with a tetradentate aminopyridine ligand were generated in the gas phase, spectroscopically characterized, and their reactivities in hydrogen-transfer and oxygen-transfer reactions were compared. The spin states were unambiguously assigned based on helium tagging infrared photodissociation (IRPD) spectra of the mass-selected iron complexes. It is shown that the stretching vibrations of the nitrate counterion can be used as a spectral marker of the central iron spin state This research was supported by the European Research Council (StG ISORI and BIDECASEOX), the Grant agency of the Czech Republic (14-20077S), the Spanish MINECO (CTQ2012-37420-C02-01/BQU), and an ICREA Academia Award to M.C. Computational resources were provided by the MetaCentrum under the program LM2010005 and the CERIT-SC under the program Centre CERIT Scientific Cloud, part of the Operational Program Research and Development for Innovations, Reg. no. CZ.1.05/3.2.00/08.0144 |
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| http://hdl.handle.net/2072/320966 | |
| eng | |
| Wiley-VCH Verlag | |
| Attribution-NonCommercial 3.0 Spain | |
| http://creativecommons.org/licenses/by-nc/3.0/es/ | |
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Catalitzadors
Catalysts Espectroscòpia infraroja Infrared spectroscopy Ferro -- Compostos -- Oxidació Iron compounds -- Oxidation Espectrometria de masses Mass spectrometry |
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| Spectroscopic Characterization and Reactivity of Triplet and Quintet Iron(IV) Oxo Complexes in the Gas Phase | |
| info:eu-repo/semantics/article | |
| Recercat |
