Ítem
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Ministerio de Economía y Competitividad (Espanya)
Ministerio de Ciencia e Innovación (Espanya) Generalitat de Catalunya. Agència de Gestió d’Ajuts Universitaris i de Recerca |
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Mitra, Mainak
Lloret Fillol, Julio Haukka, Matti Costas Salgueiro, Miquel Nordlander, Ebbe |
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| 2014 | |
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A new iron complex mediates stereospecific hydroxylation of alkyl C-H bonds with hydrogen peroxide, exhibiting excellent efficiency. Isotope labelling studies provide evidence that the relative reactivity of tautomerically related oxo-iron species responsible for the C-H hydroxylation reaction is dominated by steric factors This work has been supported by the European Union (the Erasmus Mundus program), the International Research Training Group Metal Sites in Biomolecules: Structures, Regulation and Mechanisms (www.biometals.eu), and COST Action CM1003. M.C. acknowledges ERC-29910, MINECO of Spain for CTQ2012- 37420-C02-01/BQU and CSD2010-00065, catalan DIUE (2009SGR637) and an ICREA academia award. J.Ll. thanks MICINN for a RyC contract |
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| application/pdf | |
| http://hdl.handle.net/10256/12102 | |
| eng | |
| Royal Society of Chemistry (RSC) | |
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info:eu-repo/semantics/altIdentifier/doi/10.1039/c3cc47830k info:eu-repo/semantics/altIdentifier/issn/1359-7345 info:eu-repo/semantics/altIdentifier/eissn/1364-548X MICINN/PN 2010-2016/CSD2010-00065 AGAUR/2009-2014/2009 SGR-637 |
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| info:eu-repo/grantAgreement/MINECO//CTQ2012-37420-C02-01/ES/DISEÑO BIOINSPIRADO DE CATALIZADORES PARA LA OXIDACION DE ENLACES C-H, C=C Y AGUA/ | |
| Attribution-NonCommercial 3.0 Spain | |
| http://creativecommons.org/licenses/by-nc/3.0/es/ | |
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Oxidació
Oxidation Ferro -- Compostos Iron compounds Catàlisi Catalysis |
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| Evidence that steric factors modulate reactivity of tautomeric iron-oxo species in stereospecific alkane C-H hydroxylation | |
| info:eu-repo/semantics/article | |
| DUGiDocs |
