Ítem
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Ministerio de Ciencia e Innovación (Espanya)
Generalitat de Catalunya. Agència de Gestió d’Ajuts Universitaris i de Recerca |
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| Swart, Marcel | |
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Through extensive molecular modelling of FeIII/IV-oxo and FeIII-hydroxo complexes it is shown here unambiguously that the assignment of the iron oxidation state of a Sc3+-capped iron-oxygen species should be revised. Iron in this Lewis-acid capped metal-bound oxygen system is FeIII, coinciding with water as a secondary axial ligand to scandium The following organizations are thanked for financial support: the Ministerio de Ciencia e Innovacion (MICINN, project number CTQ2011-25086/BQU) and the DIUE of the Generalitat de Catalunya (project number 2009SGR528, and Xarxa de Referencia en Quimica Teorica i Computacional). Financial support was provided by MICINN (Ministry of Science and Innovation, Spain) and the FEDER fund (European Fund for Regional Development) under grant UNGI08-4E-003 |
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| http://hdl.handle.net/2072/296710 | |
| eng | |
| Royal Society of Chemistry (RSC) | |
| Tots els drets reservats | |
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Ferro -- Oxidació
Iron -- Oxidation |
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| A change in the oxidation state of iron: Scandium is not innocent | |
| info:eu-repo/semantics/article | |
| Recercat |
