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| Ministerio de Ciencia e Innovación (Espanya) | |
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Schröder, Kristin
Join, Benoët Amali, Arlin Jose Junge, Kathrin Ribas Salamaña, Xavi Costas Salgueiro, Miquel Beller, Matthias |
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El mateix article està publicat en alemany a l’edició alemanya d’ ’Angewandte Chemie’ (ISSN 0044-8249, EISSN 1521-3757), 2011, vol. 123, núm. 6, p.1461–1465. DOI http://dx.doi.org/10.1002/ange.201004623 It’s no sacrifice: A bio-inspired iron system, in which a β-keto ester serves as a sacrificial cosubstrate, readily epoxidizes olefins under ambient conditions with air. Aromatic olefins are oxidized in high yields with excellent chemoselectivity. Mechanistic investigations point out substantial differences to well-known radical-based autoxidations M.C. thanks MICINN for project CTQ2009-08464/BQU, Generalitat de Catalunya for an ICREA Academia Award, and UdG STR for experimental support |
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| http://hdl.handle.net/2072/297585 | |
| eng | |
| Wiley-VCH Verlag | |
| Tots els drets reservats | |
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Epòxids
Epoxy compounds Imidazoles Ferro Iron Alquens Alkenes |
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| A biomimetic iron catalyst for the epoxidation of olefins with molecular oxygen at room temperature | |
| info:eu-repo/semantics/article | |
| Recercat |
