Ítem
|
Comisión Interministerial de Ciencia y Tecnología (Espanya)
Ministerio de Educación y Ciencia (Espanya) |
|
|
Ribas Salamaña, Xavi
Xifra Garcia, Raül Parella Coll, Teodor Poater Teixidor, Albert Solà i Puig, Miquel Llobet Dalmases, Antoni |
|
|
Aquest mateix article està publicat a l’edició alemanya d’’Angewandte Chemie’ (ISSN 0044-8249, EISSN 1521-3757), 2006, vol.118, núm. 18, p. 3007-3010. DOI http://dx.doi.org/10.1002/ange.200504222 The first reversible and regiospecific H/D exchange promoted by CuI proceeds in weakly coordinating deuterated "acidic" solvents, such as [D6]acetone or [D 4]methanol (see scheme). The kinetics of the reaction have been studied in both directions (H/D and D/H exchange) by 1H and 2H NMR spectroscopy, and a molecular mechanism is proposed that is in accordance with all experimental and theoretical data This research was supported bythe MEC (Spain; projects BQU2003-02884, BQU2003-01677, and CTQ2005-08797-C02-01). X.R. is grateful for a Juan de la Cierva contract from MEC |
|
| http://hdl.handle.net/2072/298892 | |
| eng | |
| Wiley | |
| Tots els drets reservats | |
|
Enllaços químics
Chemical bonds Funcional de densitat, Teoria del Density functionals Coure Copper Activació (Química) Activation (Chemistry) |
|
| Regiospecific C-H bond activation: Reversible H/D exchange promoted by CuI complexes with triazamacrocyclic ligands | |
| info:eu-repo/semantics/article | |
| Recercat |
